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On-site extraction of benzophenones from swimming pool water using hybrid tapes based on the integration of hydrophilic-lipophilic balance microparticles and an outer magnetic nanometric domain.
Belhameid, Ahmed; Casado-Carmona, Francisco Antonio; Megriche, Adel; López-Lorente, Ángela Inmaculada; Lucena, Rafael; Cárdenas, Soledad.
Afiliación
  • Belhameid A; Affordable and Sustainable Sample Preparation (AS2P) Research Group, Departamento de Química Analítica, Instituto Químico para la Energía y el Medioambiente IQUEMA, Universidad de Córdoba, Campus de Rabanales, Edificio Marie Curie, E-14071, Córdoba, Spain.
  • Casado-Carmona FA; Laboratory of Applied Mineral Chemistry, Faculty of Sciences of Tunis, University of Tunis El Manar, University, Campus El Manar 1, 2092, Tunis, Tunisia.
  • Megriche A; Affordable and Sustainable Sample Preparation (AS2P) Research Group, Departamento de Química Analítica, Instituto Químico para la Energía y el Medioambiente IQUEMA, Universidad de Córdoba, Campus de Rabanales, Edificio Marie Curie, E-14071, Córdoba, Spain.
  • López-Lorente ÁI; FI-TRACE Group, Department of Chemistry, Faculty of Science, University of the Balearic Islands, Illes Balears, Carretera de Valldemossa Km 7.5, E-07122, Palma de Mallorca, Spain.
  • Lucena R; Laboratory of Applied Mineral Chemistry, Faculty of Sciences of Tunis, University of Tunis El Manar, University, Campus El Manar 1, 2092, Tunis, Tunisia.
  • Cárdenas S; Affordable and Sustainable Sample Preparation (AS2P) Research Group, Departamento de Química Analítica, Instituto Químico para la Energía y el Medioambiente IQUEMA, Universidad de Córdoba, Campus de Rabanales, Edificio Marie Curie, E-14071, Córdoba, Spain. q32loloa@uco.es.
Mikrochim Acta ; 191(9): 513, 2024 Aug 06.
Article en En | MEDLINE | ID: mdl-39105990
ABSTRACT
An on-site extraction device is presented consisting of scotch tape modified with concentric domains of micrometric hydrophilic-lipophilic balance (HLB) particles surrounded by a ring of nanometric magnetic ones. On the one hand, HLB microparticles are readily available at the surface of the tape, exposed to interact with the target analytes, being responsible for the extraction capacity of the sorptive phase. On the other hand, the presence of magnetic nanoparticles enables the attachment of the modified tape onto a metallic screw via a magnet, which is then coupled to a wireless drill, enabling the stirring of the microextraction device. Both are simply fixed to the cost-effective, flexible, and versatile support, i.e., scotch tape, owing to their adhesive properties. The microextraction device has been applied to the determination of six benzophenones in swimming pool water samples. The variables that may affect the extraction process have been evaluated. Under the optimum conditions and using liquid chromatography-tandem mass spectrometry as the instrumental technique, the method provided a limit of detection of 0.03 µg L-1. The intra-day precision, evaluated at three different concentration levels and expressed as relative standard deviation, was lower than 10%, which also comprises the variability within single-use sorptive tapes. The accuracy, calculated with spiked samples and expressed as relative recovery, ranged from 71 to 138%. The method was applied to the analysis of swimming pool water, revealing the presence of such compounds.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Mikrochim Acta Año: 2024 Tipo del documento: Article País de afiliación: España Pais de publicación: Austria
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Mikrochim Acta Año: 2024 Tipo del documento: Article País de afiliación: España Pais de publicación: Austria