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Synthesis and Characterization of ZnO and TiO2 Hybrid Coatings for Textile UV Anti-Aging Protection.
Somogyi Skoc, Maja; Macan, Jelena; Jakovljevic, Suzana; Rezic, Iva.
Afiliación
  • Somogyi Skoc M; Department of Materials, Fibres and Textile Testing, Faculty of Textile Technology, University of Zagreb, Prilaz baruna Filipovica 28a, HR-10000 Zagreb, Croatia.
  • Macan J; Faculty of Chemical Engineering and Technology, University of Zagreb, Marulicev trg 19, HR-10001 Zagreb, Croatia.
  • Jakovljevic S; Faculty of Mechanical Engineering and Naval Architecture, University of Zagreb, Ul. Ivana Lucica 5, HR-10000 Zagreb, Croatia.
  • Rezic I; Department of Applied Chemistry, Faculty of Textile Technology, University of Zagreb, HR-10000 Zagreb, Croatia.
Polymers (Basel) ; 16(14)2024 Jul 12.
Article en En | MEDLINE | ID: mdl-39065318
ABSTRACT
The aim of this study was to prepare and characterize thin hybrid films on polyurethane-coated knitted fabrics and to achieve satisfactory color fastness to artificial light. Sol-gel-derived hybrid thin films were deposited via the dip-coating of 3-glycidoxypropiltrimethoxysilane. Titanium dioxide (TiO2) and zinc oxide (ZnO) nanopowders were added to compensate for the insufficient aging resistance, which manifests itself in low color fastness and is one of the most frequent complaints from manufacturers of coated marine fabrics (yachts, boats, etc.). The optimum processing conditions were determined by varying the concentration of precursors and auxiliaries, the mass concentration of TiO2 and ZnO nanopowders, the drawing speed, and the methods and process of fabric treatment. The hybrid films were also characterized using scanning electron microscopy and Fourier transform infrared spectroscopy with attenuated total internal reflection, while Spectraflash SF 300 investigated color fastness. After 300 h of exposure in a xenon chamber, the thin hybrid films showed good color fastness and good resistance to washing cycles. The sol-gel treatment proved to be a successful answer to the manufacturers' need for the post-treatment of polyurethane-coated knitted fabrics against UV radiation for use in the marine sector (yachts, speedboats, etc.).
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Polymers (Basel) Año: 2024 Tipo del documento: Article País de afiliación: Croacia Pais de publicación: Suiza

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Polymers (Basel) Año: 2024 Tipo del documento: Article País de afiliación: Croacia Pais de publicación: Suiza