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Baeyer-Villiger oxidation: a promising tool for the synthesis of natural products: a review.
Fatima, Summaya; Zahoor, Ameer Fawad; Khan, Samreen Gul; Naqvi, Syed Ali Raza; Hussain, Syed Makhdoom; Nazeer, Usman; Mansha, Asim; Ahmad, Hamad; Chaudhry, Aijaz Rasool; Irfan, Ahmad.
Afiliación
  • Fatima S; Department of Chemistry, Government College University Faisalabad 38000 Faisalabad Pakistan fawad.zahoor@gcuf.edu.pk.
  • Zahoor AF; Department of Chemistry, Government College University Faisalabad 38000 Faisalabad Pakistan fawad.zahoor@gcuf.edu.pk.
  • Khan SG; Department of Chemistry, Government College University Faisalabad 38000 Faisalabad Pakistan fawad.zahoor@gcuf.edu.pk.
  • Naqvi SAR; Department of Chemistry, Government College University Faisalabad 38000 Faisalabad Pakistan fawad.zahoor@gcuf.edu.pk.
  • Hussain SM; Department of Zoology, Government College University Faisalabad 38000 Faisalabad Pakistan.
  • Nazeer U; Department of Chemistry, University of Houston 3585 Cullen Boulevard Texas 77204-5003 USA.
  • Mansha A; Department of Chemistry, Government College University Faisalabad 38000 Faisalabad Pakistan fawad.zahoor@gcuf.edu.pk.
  • Ahmad H; Department of Chemistry, University of Management and Technology Lahore 54000 Pakistan.
  • Chaudhry AR; Department of Physics, College of Science, University of Bisha PO Box 551 Bisha 61922 Saudi Arabia.
  • Irfan A; Department of Chemistry, College of Science, King Khalid University PO Box 9004 Abha 61413 Saudi Arabia.
RSC Adv ; 14(32): 23423-23458, 2024 Jul 19.
Article en En | MEDLINE | ID: mdl-39055269
ABSTRACT
Baeyer-Villiger oxidation is a well-known reaction utilized for the synthesis of lactones and ester functionalities from ketones. Chiral lactones can be synthesized from chiral or racemic ketones by employing asymmetric Baeyer-Villiger oxidation. These lactones act as key intermediates in the synthesis of most of the biologically active natural products, their analogues, and derivatives. Various monooxygenases and oxidizing agents facilitate BV oxidation, providing a broad range of synthetic applications in organic chemistry. The variety of enzymatic and chemoselective Baeyer-Villiger oxidations and their substantial role in the synthesis of natural products i.e., alkaloids, polyketides, fatty acids, terpenoids, etc. (reported since 2018) have been summarized in this review article.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: RSC Adv Año: 2024 Tipo del documento: Article Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: RSC Adv Año: 2024 Tipo del documento: Article Pais de publicación: Reino Unido