Optical properties investigation and multicolor behavior of neodymium (Nd3+)-doped oxyfluoride silicate glasses SiO2-PbO-PbF2.
Luminescence
; 39(7): e4832, 2024 Jul.
Article
en En
| MEDLINE
| ID: mdl-39031322
ABSTRACT
The aim of this research is to investigate novel compositions of oxyfluoride glasses doped with Neodymium (Nd3+) rare earth ions in the visible spectrum. This area has not been extensively studied in the existing literature, so it is vital to understand the favorable photoluminescence characteristics within this part of the electromagnetic spectrum. Therefore, we synthesized and characterized SiO2-PbO-PbF2 (SPF) doped with 1% neodymium (Nd3+) ions glasses. Spectroscopic analyses, based on Judd-Ofelt theory, were conducted on absorption spectra. These analyses enabled to determine absorption cross-sections, transition probabilities, and Judd-Ofelt intensity parameters Ω2, Ω4, and Ω6 for the different transition. Additionally, we calculated various radiative properties, such as branching ratios, integrated cross-sections, radiative lifetimes, emission cross-section, optical gain, and the multicolor behavior (chromaticity coordinates, CIE diagram) under different excitation wavelengths. The results suggest promising prospects for using these oxyfluoride silicate glasses doped with Nd3+ as a fluorophore, potentially for lasing materials around 630-nm emission and in other photonic applications.
Palabras clave
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Silicatos
/
Dióxido de Silicio
/
Vidrio
/
Neodimio
Idioma:
En
Revista:
Luminescence
Asunto de la revista:
BIOFISICA
/
BIOQUIMICA
Año:
2024
Tipo del documento:
Article
País de afiliación:
Argelia
Pais de publicación:
Reino Unido