Modulation of Fe-Fe distance and spin in diiron complexes using tetradentate ligands with different flanking donors.

Spielvogel, Kyle D; Campbell, Emily J; Chowdhury, Sabyasachi Roy; Benner, Florian; Demir, Selvan; Hatzis, Gillian P; Petras, Hayley R; Sembukuttiarachchige, Dunya; Shepherd, James J; Thomas, Christine M; Vlaisavljevich, Bess; Daly, Scott R

Spielvogel, Kyle D; Campbell, Emily J; Chowdhury, Sabyasachi Roy; Benner, Florian; Demir, Selvan; Hatzis, Gillian P; Petras, Hayley R; Sembukuttiarachchige, Dunya; Shepherd, James J; Thomas, Christine M; Vlaisavljevich, Bess; Daly, Scott R.

Afiliación

Spielvogel KD; The University of Iowa, Department of Chemistry, E331 Chemistry Building, Iowa City, IA 52242, USA. scott-daly@uiowa.edu.
Campbell EJ; The University of Iowa, Department of Chemistry, E331 Chemistry Building, Iowa City, IA 52242, USA. scott-daly@uiowa.edu.
Chowdhury SR; The University of South Dakota, Department of Chemistry, 414 E Clark St., Vermillion SD, 57069, USA.
Benner F; Michigan State University, Department of Chemistry, 578 South Shaw Lane, East Lansing, Michigan 48824, USA.
Demir S; Michigan State University, Department of Chemistry, 578 South Shaw Lane, East Lansing, Michigan 48824, USA.
Hatzis GP; The Ohio State University, Department of Chemistry and Biochemistry, 100 West 18th Ave, Columbus, OH 43210, USA.
Petras HR; The University of Iowa, Department of Chemistry, E331 Chemistry Building, Iowa City, IA 52242, USA. scott-daly@uiowa.edu.
Sembukuttiarachchige D; The University of Iowa, Department of Chemistry, E331 Chemistry Building, Iowa City, IA 52242, USA. scott-daly@uiowa.edu.
Shepherd JJ; The University of Iowa, Department of Chemistry, E331 Chemistry Building, Iowa City, IA 52242, USA. scott-daly@uiowa.edu.
Thomas CM; The Ohio State University, Department of Chemistry and Biochemistry, 100 West 18th Ave, Columbus, OH 43210, USA.
Vlaisavljevich B; The University of Iowa, Department of Chemistry, E331 Chemistry Building, Iowa City, IA 52242, USA. scott-daly@uiowa.edu.
Daly SR; The University of South Dakota, Department of Chemistry, 414 E Clark St., Vermillion SD, 57069, USA.

Chem Commun (Camb) ; 60(64): 8399-8402, 2024 Aug 06.

Article en En | MEDLINE | ID: mdl-39028006

ABSTRACT

ABSTRACT

Here we report the synthesis and characterization of diiron complexes containing triaryl N4 and N2S2 ligands derived from o-phenylenediamine. The complexes display significant differences in Fe-Fe distances and magnetic properties that depend on the identity of the flanking NMe2 and SMe donor groups.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Reino Unido

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