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Association of Metal Cations with the Anti-PF4/Heparin Antibody Response in Heparin-Induced Thrombocytopenia.
Giles, Jason B; Martinez, Kiana L; Steiner, Heidi E; Klein, Andrew; Ooi, Aikseng; Pryor, Julie; Sweitzer, Nancy; Fuchs, Deborah; Karnes, Jason H.
Afiliación
  • Giles JB; Lifecourse Epidemiology of Adiposity and Diabetes (LEAD) Center, University of Colorado Anschutz Medical Campus, Aurora, CO, USA.
  • Martinez KL; Department of Pharmacy Practice and Science, University of Arizona College of Pharmacy, 1295 N Martin AVE, Tucson, AZ, 85721, USA.
  • Steiner HE; Department of Pharmacy Practice and Science, University of Arizona College of Pharmacy, 1295 N Martin AVE, Tucson, AZ, 85721, USA.
  • Klein A; Department of Pharmacy Practice and Science, University of Arizona College of Pharmacy, 1295 N Martin AVE, Tucson, AZ, 85721, USA.
  • Ooi A; Department of Pharmacology and Toxicology, University of Arizona College of Pharmacy, Tucson, AZ, USA.
  • Pryor J; Banner University Medical Center-Tucson, Tucson, AZ, USA.
  • Sweitzer N; John T Milliken Department of Internal Medicine, Washington University School of Medicine, St Louis, MO, USA.
  • Fuchs D; Banner University Medical Center-Tucson, Tucson, AZ, USA.
  • Karnes JH; Department of Pharmacy Practice and Science, University of Arizona College of Pharmacy, 1295 N Martin AVE, Tucson, AZ, 85721, USA. karnes@arizona.edu.
Cardiovasc Toxicol ; 24(9): 968-981, 2024 Sep.
Article en En | MEDLINE | ID: mdl-39017812
ABSTRACT
Heparin-induced thrombocytopenia (HIT) is an antibody-mediated immune response against complexes of heparin and platelet factor 4 (PF4). The electrostatic interaction between heparin and PF4 is critical for the anti-PF4/heparin antibody response seen in HIT. The binding of metal cations to heparin induces conformational changes and charge neutralization of the heparin molecule, and cation-heparin binding can modulate the specificity and affinity for heparin-binding partners. However, the effects of metal cation binding to heparin in the context of anti-PF4/heparin antibody response have not been determined. Here, we utilized inductively coupled plasma mass spectrometry (ICP-MS) to quantify 16 metal cations in patient plasma and tested for correlation with anti-PF4/heparin IgG levels and platelet count after clinical suspicion of HIT in a cohort of heparin-treated patients. The average age of the cohort (n = 32) was 60.53 (SD = 14.31) years old, had a mean anti-PF4/heparin antibody optical density [OD405] of 0.93 (SD = 1.21) units, and was primarily female (n = 23). Patients with positive anti-PF4/heparin antibody test results (OD405 ≥ 0.5 units) were younger, had increased weight and BMI, and were more likely to have a positive serotonin release assay (SRA) result compared to antibody-negative patients. We observed statistical differences between antibody-positive and -negative groups for sodium and aluminum and significant correlations of anti-PF4/heparin antibody levels with sodium and silver. While differences in sodium concentrations were associated with antibody-positive status and correlated with antibody levels, no replication was performed. Additional studies are warranted to confirm our observed association, including in vitro binding studies and larger observational cohorts.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Trombocitopenia / Factor Plaquetario 4 / Heparina / Anticoagulantes Límite: Adult / Aged / Female / Humans / Male / Middle aged Idioma: En Revista: Cardiovasc Toxicol Asunto de la revista: ANGIOLOGIA / CARDIOLOGIA / TOXICOLOGIA Año: 2024 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Trombocitopenia / Factor Plaquetario 4 / Heparina / Anticoagulantes Límite: Adult / Aged / Female / Humans / Male / Middle aged Idioma: En Revista: Cardiovasc Toxicol Asunto de la revista: ANGIOLOGIA / CARDIOLOGIA / TOXICOLOGIA Año: 2024 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos