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Steam-Assisted Selective CO2 Hydrogenation to Ethanol over Ru-In Catalysts.
Zhou, Chengshuang; Aitbekova, Aisulu; Liccardo, Gennaro; Oh, Jinwon; Stone, Michael L; McShane, Eric J; Werghi, Baraa; Nathan, Sindhu; Song, Chengyu; Ciston, Jim; Bustillo, Karen C; Hoffman, Adam S; Hong, Jiyun; Perez-Aguilar, Jorge; Bare, Simon R; Cargnello, Matteo.
Afiliación
  • Zhou C; Department of Chemical Engineering, Stanford University, Stanford, California, 94305, United States.
  • Aitbekova A; Applied Physics and Materials Science, California Institute of Technology, Pasadena, California, 91125, United States.
  • Liccardo G; Department of Chemical Engineering, Stanford University, Stanford, California, 94305, United States.
  • Oh J; SUNCAT Center for Interface Science and Catalysis, Stanford University, Stanford, California, 94305, United States.
  • Stone ML; Department of Materials Science and Engineering, Stanford University, Stanford, California, 94305, United States.
  • McShane EJ; Department of Chemical Engineering, Stanford University, Stanford, California, 94305, United States.
  • Werghi B; Department of Chemical Engineering, Stanford University, Stanford, California, 94305, United States.
  • Nathan S; Department of Chemical Engineering, Stanford University, Stanford, California, 94305, United States.
  • Song C; SUNCAT Center for Interface Science and Catalysis, Stanford University, Stanford, California, 94305, United States.
  • Ciston J; SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California, 94305, United States.
  • Bustillo KC; Department of Chemical Engineering, Stanford University, Stanford, California, 94305, United States.
  • Hoffman AS; National Center for Electron Microscopy Facility, Molecular Foundry, Lawrence Berkeley National Lab, Berkeley, California, 94720, United States.
  • Hong J; National Center for Electron Microscopy Facility, Molecular Foundry, Lawrence Berkeley National Lab, Berkeley, California, 94720, United States.
  • Perez-Aguilar J; National Center for Electron Microscopy Facility, Molecular Foundry, Lawrence Berkeley National Lab, Berkeley, California, 94720, United States.
  • Bare SR; SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California, 94305, United States.
  • Cargnello M; SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California, 94305, United States.
Angew Chem Int Ed Engl ; 63(41): e202406761, 2024 Oct 07.
Article en En | MEDLINE | ID: mdl-38990707
ABSTRACT
Multicomponent catalysts can be designed to synergistically combine reaction intermediates at interfacial active sites, but restructuring makes systematic control and understanding of such dynamics challenging. We here unveil how reducibility and mobility of indium oxide species in Ru-based catalysts crucially control the direct, selective conversion of CO2 to ethanol. When uncontrolled, reduced indium oxide species occupy the Ru surface, leading to deactivation. With the addition of steam as a mild oxidant and using porous polymer layers to control In mobility, Ru-In2O3 interface sites are stabilized, and ethanol can be produced with superior overall selectivity (70 %, rest CO). Our work highlights how engineering of bifunctional active ensembles enables cooperativity and synergy at tailored interfaces, which unlocks unprecedented performance in heterogeneous catalysts.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2024 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Alemania
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2024 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Alemania