Polarizing Perspectives: Ion- and Dipole-Induced Dipole Interactions Dictate Bulk Nanobubble Stability.

Karimi, Mohammadjavad; Parsafar, Gholamabbas; Samouei, Hamidreza

Karimi, Mohammadjavad; Parsafar, Gholamabbas; Samouei, Hamidreza.

Afiliación

Karimi M; Department of Petroleum Engineering, Texas A&M University, College Station, Texas 77843, United States.
Parsafar G; Department of Petroleum Engineering, Texas A&M University, College Station, Texas 77843, United States.
Samouei H; Department of Petroleum Engineering, Texas A&M University, College Station, Texas 77843, United States.

J Phys Chem B ; 128(29): 7263-7270, 2024 Jul 25.

Article en En | MEDLINE | ID: mdl-38990291

ABSTRACT

ABSTRACT

The origin of the stability of bulk Nanobubbles (NBs) has been the object of scrutiny in recent years. The interplay between the surface charge on the NBs and the Laplace pressure resulting from the surface tension at the solvent-NB interface has often been evoked to explain the stability of the dispersed NBs. While the Laplace pressure is well understood in the community, the nature of the surface charge on the NBs has remained obscure. In this work, we aim to show that the solvent and the present ions can effectively polarize the NB surface by inducing a dipole moment, which in turn controls the NB stability. We show that the polarizability of the dispersed gas and the polarity of the dispersing solvent control the dipole-induced dipole interactions between the solvent and the NBs, and that, in turn, determines their stability in solution.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Phys Chem B Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos

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