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A pH-dependent and charge selective covalent organic framework for removal of dyes from aqueous solutions.
Rastegari, Forouz; Asghari, Saeid; Mohammadpoor-Baltork, Iraj; Sabzyan, Hassan; Tangestaninejad, Shahram; Moghadam, Majid; Mirkhani, Valiollah.
Afiliación
  • Rastegari F; Department of Chemistry, Catalysis Division, University of Isfahan, Isfahan 81746-73441, Iran.
  • Asghari S; Department of Chemistry, Catalysis Division, University of Isfahan, Isfahan 81746-73441, Iran.
  • Mohammadpoor-Baltork I; Department of Chemistry, Catalysis Division, University of Isfahan, Isfahan 81746-73441, Iran. Electronic address: imbaltork@sci.ui.ac.ir.
  • Sabzyan H; Department of Chemistry, University of Isfahan, Isfahan 81746-73441, Iran.
  • Tangestaninejad S; Department of Chemistry, Catalysis Division, University of Isfahan, Isfahan 81746-73441, Iran.
  • Moghadam M; Department of Chemistry, Catalysis Division, University of Isfahan, Isfahan 81746-73441, Iran.
  • Mirkhani V; Department of Chemistry, Catalysis Division, University of Isfahan, Isfahan 81746-73441, Iran.
J Hazard Mater ; 476: 135075, 2024 Sep 05.
Article en En | MEDLINE | ID: mdl-38986412
ABSTRACT
A novel imine-linked COF is synthesized by the condensation of 2,4,6-tris(4-aminophenyl)-1,3,5-triazine (TAPT) and 2-hydroxy-5-methoxyisophthalaldehyde (HMIPA) under solvothermal conditions. This COF adsorbs preferentially the neutral dye Neutral Red (NR) over the positively charged dye Methylene Blue (MB) at pH 7, and the negatively charged Methyl Orange (MO) over the positively charged Methylene Blue (MB) at pH 3. The maximum adsorption capacities (qe) obtained within very short times (11-60 min) under optimized conditions were 108, 185 and 429 mg.g-1 for the MB, MO, and NR dyes, respectively. These adsorptions obey the Langmuir isotherm and pseudo-second-order kinetics. The prepared TAPT-HMIPA-COF is used successfully for the removal of the dyes from real water and treated wastewater samples. The adsorption data, BET, FTIR, and zeta potential measurements show that the electrostatic, π-π stacking and hydrogen bond interactions are responsible for the adsorption of organic dyes on the surface of the prepared COF. Due to recyclability, high capacity and efficiency for the adsorption of positive, negative and neutral organic dyes, this COF can be considered promising for simultaneous removal of various dyes from aqueous solutions at adjusted pHs.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Hazard Mater Asunto de la revista: SAUDE AMBIENTAL Año: 2024 Tipo del documento: Article País de afiliación: Irán Pais de publicación: Países Bajos
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Hazard Mater Asunto de la revista: SAUDE AMBIENTAL Año: 2024 Tipo del documento: Article País de afiliación: Irán Pais de publicación: Países Bajos