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Designed Synthesis of an Aluminum Molecular Ring Based Rotaxane and Polyrotaxane.
Liu, Ya-Jie; Zheng, Chan; Xiao, Han; Wang, Zirui; Zhang, Cheng-Yang; Wang, San-Tai; Fang, Wei-Hui; Zhang, Jian.
Afiliación
  • Liu YJ; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, P. R. China.
  • Zheng C; University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing, 100049, P. R. China.
  • Xiao H; School of Materials Science and Engineering, Fujian University of Technology, 3 Xueyuan Road, Fuzhou, Fujian, 350108, P. R. China.
  • Wang Z; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, P. R. China.
  • Zhang CY; University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing, 100049, P. R. China.
  • Wang ST; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, P. R. China.
  • Fang WH; University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing, 100049, P. R. China.
  • Zhang J; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, P. R. China.
Angew Chem Int Ed Engl ; 63(45): e202411576, 2024 Nov 04.
Article en En | MEDLINE | ID: mdl-38984566
ABSTRACT
Mechanically interlocked molecules, such as rotaxanes, have drawn significant attention within supramolecular chemistry. Although a variety of macrocycles have been thoroughly explored in rotaxane synthesis, metal-organic macrocycles remain relatively under-investigated. Aluminum molecular rings, with their inner cavities and numerous binding sites, present a promising option for constructing rotaxanes. Here, we introduce an innovative "ring-donor⋅⋅⋅axle-acceptor" motif utilizing Al8 molecular rings, enabling the stepwise assembly of molecules, complexes, and polymers through tailored coordination chemistry. This novel approach can not only be applied to macrocycle-based systems like catenanes but also enhance specific functionalities progressively.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2024 Tipo del documento: Article Pais de publicación: Alemania
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2024 Tipo del documento: Article Pais de publicación: Alemania