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Synthesis of 2-benzyl N-substituted anilines via imine condensation-isoaromatization of (E)-2-arylidene-3-cyclohexenones and primary amines.
Li, Lu; Li, Na; Mo, Xiao-Tian; Yuan, Ming-Wei; Jiang, Lin; Yuan, Ming-Long.
Afiliación
  • Li L; National and Local Joint Engineering Research Center for Green Preparation Technology of Biobased Materials; School of Chemistry and Environment, Yunnan Minzu University, Kunming, China.
  • Li N; National and Local Joint Engineering Research Center for Green Preparation Technology of Biobased Materials; School of Chemistry and Environment, Yunnan Minzu University, Kunming, China.
  • Mo XT; National and Local Joint Engineering Research Center for Green Preparation Technology of Biobased Materials; School of Chemistry and Environment, Yunnan Minzu University, Kunming, China.
  • Yuan MW; National and Local Joint Engineering Research Center for Green Preparation Technology of Biobased Materials; School of Chemistry and Environment, Yunnan Minzu University, Kunming, China.
  • Jiang L; National and Local Joint Engineering Research Center for Green Preparation Technology of Biobased Materials; School of Chemistry and Environment, Yunnan Minzu University, Kunming, China.
  • Yuan ML; National and Local Joint Engineering Research Center for Green Preparation Technology of Biobased Materials; School of Chemistry and Environment, Yunnan Minzu University, Kunming, China.
Beilstein J Org Chem ; 20: 1468-1475, 2024.
Article en En | MEDLINE | ID: mdl-38978743
ABSTRACT
A catalyst- and additive-free synthesis of 2-benzyl N-substituted anilines from (E)-2-arylidene-3-cyclohexenones and primary amines has been reported. The reaction proceeds smoothly through a sequential imine condensation-isoaromatization pathway, affording a series of synthetically useful aniline derivatives in acceptable to high yields. Mild reaction conditions, no requirement of metal catalysts, operational simplicity and the potential for scale-up production are some of the highlighted advantages of this transformation.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Beilstein J Org Chem Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Alemania
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Beilstein J Org Chem Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Alemania