Your browser doesn't support javascript.
loading
Thermally Annealed High-Aspect-Ratio ZIF-8 Nanoplates-Incorporated Mixed Matrix Membranes for Improved H2/CO2 Selectivity.
Jia, Yan; Chen, Kaiyi; Liu, Pengxiao; Liu, Yubo; Pi, Xingjian; Zhang, Xiaocan; Zhang, Ying.
Afiliación
  • Jia Y; College of New Energy and Materials, China University of Petroleum (Beijing), Changping District, Beijing 102249, PR China.
  • Chen K; College of Chemical Engineering and Environment, China University of Petroleum (Beijing), Changping District, Beijing 102249, PR China.
  • Liu P; College of New Energy and Materials, China University of Petroleum (Beijing), Changping District, Beijing 102249, PR China.
  • Liu Y; China Offshore Oil Engineering (Qingdao) Co., limited, Huangdao District, Qingdao 266400, PR China.
  • Pi X; College of New Energy and Materials, China University of Petroleum (Beijing), Changping District, Beijing 102249, PR China.
  • Zhang X; College of Science, China University of Petroleum (Beijing), Changping District, Beijing 102249, PR China.
  • Zhang Y; College of New Energy and Materials, China University of Petroleum (Beijing), Changping District, Beijing 102249, PR China.
ACS Appl Mater Interfaces ; 16(28): 37100-37110, 2024 Jul 17.
Article en En | MEDLINE | ID: mdl-38968215
ABSTRACT
The main challenge in the preparation of MOF-based mixed matrix membranes is to construct a good interface morphology to improve the gas separation performance and stability of the membranes. Herein, high-aspect-ratio ZIF-8 nanoplates for H2/CO2 separation membranes were synthesized by direct template conversion. The ZIF-8 nanoplates were prepared with the commercial Matrimid polymer to form MMMs by the flat scraping method. The homogeneous dispersion of high-aspect-ratio nanoplates in the membrane and the good compatibility between the filler and the matrix caused by the thermal annealing operation improve the gas separation performance and mechanical properties of MMMs. The H2/CO2 selectivity of MMMs loaded with 30 wt % ZIF-8 nanoplates increased to 10.3, and the H2 permeability was 330.1 Barrer. This synthesis method can be extended to prepare various ZIF nanoplates with elevated aspect ratios to obtain excellent performance fillers for gas separation of MMMs. In addition, the thermal annealing operation allows more efficient gas separation in polymer membranes and is a feasible way to design excellent and stable MMMs.
Palabras clave
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Appl Mater Interfaces Asunto de la revista: BIOTECNOLOGIA / ENGENHARIA BIOMEDICA Año: 2024 Tipo del documento: Article Pais de publicación: Estados Unidos
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Appl Mater Interfaces Asunto de la revista: BIOTECNOLOGIA / ENGENHARIA BIOMEDICA Año: 2024 Tipo del documento: Article Pais de publicación: Estados Unidos