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Ultrafast Dual-Shock Chemistry Synthesis of Ordered/Disordered Hybrid Carbon Anodes: High-Rate Performance of Li-Ion Batteries.
Huang, Pengfei; Li, Zekun; Chen, Li; Li, Yuan; Liu, Zhedong; Zhang, Jingchao; Luo, Jiawei; Zhang, Wenjun; Liu, Wei-Di; Zhang, Xinxi; Zhu, Rongtao; Chen, Yanan.
Afiliación
  • Huang P; Key Laboratory of Coal Processing and Efficient Utilization of Ministry of Education, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China.
  • Li Z; School of Materials Science and Engineering, Key Laboratory of Advanced Ceramics, Machining Technology of Ministry of Education, Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin 300072, China.
  • Chen L; School of Materials Science and Engineering, Key Laboratory of Advanced Ceramics, Machining Technology of Ministry of Education, Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin 300072, China.
  • Li Y; School of Materials Science and Engineering, Key Laboratory of Advanced Ceramics, Machining Technology of Ministry of Education, Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin 300072, China.
  • Liu Z; School of Materials Science and Engineering, Key Laboratory of Advanced Ceramics, Machining Technology of Ministry of Education, Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin 300072, China.
  • Zhang J; School of Materials Science and Engineering, Key Laboratory of Advanced Ceramics, Machining Technology of Ministry of Education, Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin 300072, China.
  • Luo J; School of Materials Science and Engineering, Key Laboratory of Advanced Ceramics, Machining Technology of Ministry of Education, Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin 300072, China.
  • Zhang W; School of Materials Science and Engineering, Key Laboratory of Advanced Ceramics, Machining Technology of Ministry of Education, Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin 300072, China.
  • Liu WD; Key Laboratory of Coal Processing and Efficient Utilization of Ministry of Education, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China.
  • Zhang X; School of Chemistry and Physics, ARC Research Hub in Zero-emission Power Generation for Carbon Neutrality, and Centre for Materials Science, Queensland University of Technology, Brisbane 4000, Australia.
  • Zhu R; Key Laboratory of Coal Processing and Efficient Utilization of Ministry of Education, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China.
  • Chen Y; Key Laboratory of Coal Processing and Efficient Utilization of Ministry of Education, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China.
ACS Nano ; 18(28): 18344-18354, 2024 Jul 16.
Article en En | MEDLINE | ID: mdl-38954797
ABSTRACT
Graphite exhibits crystal anisotropy, which impedes the mass transfer of ion intercalation and extraction processes in Li-ion batteries. Herein, a dual-shock chemical strategy has been developed to synthesize the carbon anode. This approach comprised two key phases (1) a thermal shock utilizing ultrahigh temperature (3228 K) can thermodynamically facilitate graphitization; (2) a mechanical shock (21.64 MPa) disrupting the π-π interactions in the aromatic chains of carbon can result in hybrid-structured carbon composed of crystalline and amorphous carbon. The optimized carbon (DSC-200-0.3) demonstrates a capacity of 208.61 mAh/g at a 10C rate, with a significant enhancement comparing with 15 mAh/g of the original graphite. Impressively, it maintains 81.06% capacity even after 3000 charge-discharge cycles. Dynamic process analysis reveals that this superior rate performance is attributed to a larger interlayer spacing facilitating ion transport comparing with the original graphite, disordered amorphous carbon for additional lithium storage sites, and crystallized carbon for enhanced charge transfer. The dual-shock chemical approach offers a cost-effective and efficient method to rapidly produce hybrid-structured carbon anodes, enabling 10C fast charging capabilities in lithium-ion batteries.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Nano Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Estados Unidos
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Nano Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Estados Unidos