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Synthesis of ω-Hydroxy Fatty Acid Alkyl Esters by Macrocyclic Lactones Alcoholysis Catalyzed by Homoleptic and Heteroleptic Zinc Aryloxides.
Petrus, Rafal; Matuszak, Karolina; Kinzhybalo, Vasyl.
Afiliación
  • Petrus R; Faculty of Chemistry, Wroclaw University of Science and Technology, 23 Smoluchowskiego, 50-370, Wroclaw, Poland.
  • Matuszak K; Faculty of Chemistry, Wroclaw University of Science and Technology, 23 Smoluchowskiego, 50-370, Wroclaw, Poland.
  • Kinzhybalo V; Institute of Low Temperature and Structure Research, Polish Academy of Sciences, 2 Okólna, 50-422, Wroclaw, Poland.
Chem Asian J ; : e202400526, 2024 Jun 26.
Article en En | MEDLINE | ID: mdl-38924377
ABSTRACT
A series of zinc aryloxides, [Zn4(sal-Me)8]⋅2.5(C7H8) (1), [Zn4(sal-Me)8]⋅CH2Cl2 (2), [Zn4(µ3-OR)2(sal-R)6] (3) (for R=Me (0.51), Et (0.49)), [Zn4(µ3-OMe)4(sal-Me)4(HOMe)4] (4), [Zn(sal-Me)2(py)2]⋅THF (5), {[Zn(sal-Me)2(tmbpy)] ⋅ 2(C6H5CH3)}n (6), [Zn2(sal-Me)2(THF)2Cl2] ⋅ 0.5(C6H5CH3) (7), and [Zn4(µ3-OMe)2(sal-Me)4Cl2] (8) (Hsal-Me=methyl salicylate, py=pyridine, tmbpy=4,4'-trimethylenedipyridine) were obtained that have different nuclearities and central core topologies and contain ligands of different basicity and coordination abilities.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Asian J Año: 2024 Tipo del documento: Article País de afiliación: Polonia Pais de publicación: Alemania
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Asian J Año: 2024 Tipo del documento: Article País de afiliación: Polonia Pais de publicación: Alemania