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Analytical method development and dermal absorption of gallic acid, a hair dye ingredient.
Kim, Yu Jin; Kim, Hyang Yeon; Lee, Jung Dae; Kim, Hong Yoon; Im, Jueng-Eun; Kim, Kyu-Bong.
Afiliación
  • Kim YJ; Department of Pharmacy, College of Pharmacy, Dankook University, 119 Dandae-ro, Cheonan, Chungnam 31116 Republic of Korea.
  • Kim HY; Center for Human Risk Assessment, Dankook University, 119 Dandae-ro, Cheonan, Chungnam 31116 Republic of Korea.
  • Lee JD; Department of Pharmacy, College of Pharmacy, Dankook University, 119 Dandae-ro, Cheonan, Chungnam 31116 Republic of Korea.
  • Kim HY; Center for Human Risk Assessment, Dankook University, 119 Dandae-ro, Cheonan, Chungnam 31116 Republic of Korea.
  • Im JE; Department of Pharmacy, College of Pharmacy, Dankook University, 119 Dandae-ro, Cheonan, Chungnam 31116 Republic of Korea.
  • Kim KB; Center for Human Risk Assessment, Dankook University, 119 Dandae-ro, Cheonan, Chungnam 31116 Republic of Korea.
Toxicol Res ; 40(3): 449-456, 2024 Jul.
Article en En | MEDLINE | ID: mdl-38911539
ABSTRACT
Gallic acid (GA) is a phenolic compound known as 3,4,5-trihydroxybenzoic acid. GA is used as a hair dye ingredient. It is limited to be below 4.0% in Korea. Dermal absorption rate of GA has not been reported yet. In this study, an analytical method for GA was developed and validated using high-performance liquid chromatography (HPLC) in various matrices of swab, stratum corneum (SC), skin (dermis + epidermis), and receptor fluid (RF). HPLC analysis showed acceptable linearity (r2 = 0.999-0.9998), accuracy (90.3-112.8%), and precision (0.7-13.6%) in accordance with validation guidelines by Korea Ministry of Food and Drug Safety (MFDS). The dermal absorption rate of GA was determined using Franz diffuse cells. GA (4.0%) was applied to mini pig skin of 10 µl/cm2. After 30 min application, the GA was wiped out and receptor fluid sampling was continued until 24 h. After 24 h, skin was wiped off with swab and SC was collected using tape stripping. All samples were extracted with ethanol and analyzed using the validated method. The total dermal absorption rate of GA was determined to be 2.6 ± 1.3% (24 h).
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Toxicol Res Año: 2024 Tipo del documento: Article Pais de publicación: Singapur

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Toxicol Res Año: 2024 Tipo del documento: Article Pais de publicación: Singapur