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Bidirectional photomagnetism, exciplex fluorescence and dielectric anomalies in a spin crossover Hofmann-type coordination polymer.
Chen, Yan-Ru; Ying, Ting-Ting; Chen, Yan-Cong; Liao, Pei-Yu; Ni, Zhao-Ping; Tong, Ming-Liang.
Afiliación
  • Chen YR; Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, IGCME, Guangdong Basic Research Center of Excellence for Functional Molecular Engineering, Sun Yat-Sen University Guangzhou 510275 P. R. China nizhp@mail.sysu.edu.cn tongml@mail.sysu.edu.cn.
  • Ying TT; Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, IGCME, Guangdong Basic Research Center of Excellence for Functional Molecular Engineering, Sun Yat-Sen University Guangzhou 510275 P. R. China nizhp@mail.sysu.edu.cn tongml@mail.sysu.edu.cn.
  • Chen YC; Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, IGCME, Guangdong Basic Research Center of Excellence for Functional Molecular Engineering, Sun Yat-Sen University Guangzhou 510275 P. R. China nizhp@mail.sysu.edu.cn tongml@mail.sysu.edu.cn.
  • Liao PY; Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, IGCME, Guangdong Basic Research Center of Excellence for Functional Molecular Engineering, Sun Yat-Sen University Guangzhou 510275 P. R. China nizhp@mail.sysu.edu.cn tongml@mail.sysu.edu.cn.
  • Ni ZP; Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, IGCME, Guangdong Basic Research Center of Excellence for Functional Molecular Engineering, Sun Yat-Sen University Guangzhou 510275 P. R. China nizhp@mail.sysu.edu.cn tongml@mail.sysu.edu.cn.
  • Tong ML; Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, IGCME, Guangdong Basic Research Center of Excellence for Functional Molecular Engineering, Sun Yat-Sen University Guangzhou 510275 P. R. China nizhp@mail.sysu.edu.cn tongml@mail.sysu.edu.cn.
Chem Sci ; 15(24): 9240-9248, 2024 Jun 19.
Article en En | MEDLINE | ID: mdl-38903231
ABSTRACT
Stepped spin crossover (SCO) complexes with three or more spin states have promising applications in high-order data storage, multi-switches and multi-sensors. Further synergy with other functionalities, such as luminescence and dielectric properties, will provide a good chance to develop novel multifunctional SCO materials. Here, a bent pillar ligand and luminescent pyrene guest are integrated into a three-dimensional (3D) Hofmann-type metal-organic framework (MOF) [Fe(dpoda){Au(CN)2}2]·pyrene (dpoda = 2,5-di-(pyridyl)-1,3,4-oxadiazole). The magnetic data show an incomplete and two-step SCO behavior with the sequence of 1 ↔ 1/2 ↔ 1/4. The rare bi-directional light-induced excited spin-state trapping (LIESST) effect and light-induced stepped thermal relaxation after LIESST are observed. The pyrene guests interact with dpoda ligands via offset face-to-face π⋯π interactions to form intermolecular exciplex emissions. The competition between thermal quenching and stepped SCO properties results in a complicated and stepped exciplex fluorescence. Moreover, the stepped dielectric property with higher dielectric permittivity at lower temperature may be related to the more frustrated octahedral distortion parameters in the intermediate spin states. Hence, a 3D Hofmann-type MOF with bent pillar ligands and fluorescent guests illustrates an effective way for the development of multifunctional switching materials.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Sci Año: 2024 Tipo del documento: Article Pais de publicación: Reino Unido
Texto completo
Añadir a Mi BVS
Imprimir
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Sci Año: 2024 Tipo del documento: Article Pais de publicación: Reino Unido