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Innovations in metal-organic frameworks (MOFs): Pioneering adsorption approaches for persistent organic pollutant (POP) removal.
Marghade, Deepali; Shelare, Sagar; Prakash, Chander; Soudagar, Manzoore Elahi M; Yunus Khan, T M; Kalam, M A.
Afiliación
  • Marghade D; Department of Applied Chemistry, Priyadarshini College of Engineering, Nagpur, Maharashtra, India; University Centre for Research and Development, Chandigarh University, Mohali, Punjab, 140413, India. Electronic address: deepalichem@gmail.com.
  • Shelare S; University Centre for Research and Development, Chandigarh University, Mohali, Punjab, 140413, India; Department of Mechanical Engineering, Priyadarshini College of Engineering, Nagpur, Maharashtra, India. Electronic address: sagmech24@gmail.com.
  • Prakash C; University Centre for Research and Development, Chandigarh University, Mohali, Punjab, 140413, India. Electronic address: chander.mechengg@gmail.com.
  • Soudagar MEM; Faculty of Engineering, Lishui University, 323000, Lishui, Zhejiang, PR China; Department of Mechanical Engineering, Graphic Era (Deemed to be University), Dehradun, Uttarakhand 248002, India. Electronic address: manzoor@lsu.edu.cn.
  • Yunus Khan TM; Department of Mechanical Engineering, College of Engineering, King Khalid University, Abha 61421, Saudi Arabia. Electronic address: yunus.tatagar@gmail.com.
  • Kalam MA; School of Civil and Environmental Engineering, Faculty of Engineering and Information Technology, University of Technology Sydney, Ultimo, Sydney, NSW 2007, Australia. Electronic address: mdabul.kalam@uts.edu.au.
Environ Res ; 258: 119404, 2024 Oct 01.
Article en En | MEDLINE | ID: mdl-38880323
ABSTRACT
Adsorption is a promising way to remove persistent organic pollutants (POPs), a major environmental issue. With their high porosity and vast surface areas, MOFs are suited for POP removal due to their excellent adsorption capabilities. This review addresses the intricate principles of MOF-mediated adsorption and helps to future attempts to mitigate organic water pollution. This review examines the complicated concepts of MOF-mediated adsorption, including MOF synthesis methodologies, adsorption mechanisms, and material tunability and adaptability. MOFs' ability to adsorb POPs via electrostatic forces, acid-base interactions, hydrogen bonds, and pi-pi interactions is elaborated. This review demonstrates its versatility in eliminating many types of contaminants. Functionalizing, adding metal nanoparticles, or changing MOFs after they are created can improve their performance and remove contaminants. This paper also discusses MOF-based pollutant removal issues and future prospects, including adsorption capacity, selectivity, scale-up for practical application, stability, and recovery. These obstacles can be overcome by rationally designing MOFs, developing composite materials, and improving material production and characterization. Overall, MOF technology research and innovation hold considerable promise for environmental pollution solutions and sustainable remediation. Desorption and regeneration in MOFs are also included in the review, along with methods for improving pollutant removal efficiency and sustainability. Case studies of effective MOF regeneration and scaling up for practical deployment are discussed, along with future ideas for addressing these hurdles.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Estructuras Metalorgánicas / Contaminantes Orgánicos Persistentes Idioma: En Revista: Environ Res Año: 2024 Tipo del documento: Article Pais de publicación: Países Bajos
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Estructuras Metalorgánicas / Contaminantes Orgánicos Persistentes Idioma: En Revista: Environ Res Año: 2024 Tipo del documento: Article Pais de publicación: Países Bajos