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0D/2D heterojunction constructed by Ag2S quantum dots anchored on graphdiyne (g-CnH2n-2) nanosheets for wide spectrum photocatalytic H2 evolution.
Fan, Yu; Wang, Yimin; Hao, Xuqiang; Deng, Wei; Jin, Zhiliang.
Afiliación
  • Fan Y; School of Chemistry and Chemical Engineering, North Minzu University, Yinchuan 750021, PR China; Ningxia Key Laboratory of Solar Chemical Conversion Technology, North Minzu University, Yinchuan 750021, PR China; Key Laboratory for Chemical Engineering and Technology, State Ethnic Affairs Commission,
  • Wang Y; School of Chemistry and Chemical Engineering, North Minzu University, Yinchuan 750021, PR China; Ningxia Key Laboratory of Solar Chemical Conversion Technology, North Minzu University, Yinchuan 750021, PR China; Key Laboratory for Chemical Engineering and Technology, State Ethnic Affairs Commission,
  • Hao X; School of Chemistry and Chemical Engineering, North Minzu University, Yinchuan 750021, PR China; Ningxia Key Laboratory of Solar Chemical Conversion Technology, North Minzu University, Yinchuan 750021, PR China; Key Laboratory for Chemical Engineering and Technology, State Ethnic Affairs Commission,
  • Deng W; School of Chemistry and Chemical Engineering, North Minzu University, Yinchuan 750021, PR China; Ningxia Key Laboratory of Solar Chemical Conversion Technology, North Minzu University, Yinchuan 750021, PR China; Key Laboratory for Chemical Engineering and Technology, State Ethnic Affairs Commission,
  • Jin Z; School of Chemistry and Chemical Engineering, North Minzu University, Yinchuan 750021, PR China; Ningxia Key Laboratory of Solar Chemical Conversion Technology, North Minzu University, Yinchuan 750021, PR China; Key Laboratory for Chemical Engineering and Technology, State Ethnic Affairs Commission,
J Colloid Interface Sci ; 672: 700-714, 2024 Oct 15.
Article en En | MEDLINE | ID: mdl-38870761
ABSTRACT
Precisely crafting heterojunctions for efficient charge separation is a major obstacle in the realm of photocatalytic hydrogen evolution. A 0D/2D heterojunction was successfully fabricated by anchoring Ag2S quantum dots (Ag2S QDs) onto graphdiyne (GDY) nanosheets (Ag2S QDs/GDY) using a straightforward physical mixing technique. This unique structure allows for excellent contact between GDY and Ag2S QDs, thereby enhancing the rate of charge transfer. The light absorption capabilities of Ag2S QDs/GDY extend up to 1200 nm, enabling strong absorption of light, including infrared. Through DFT calculations and in-situ XPS analysis, it was demonstrated that incorporating Ag2S QDs onto GDY effectively modulates the electronic structure, promotes an internal electric field, and facilitates directional electron transfer. This directed electron transfer enhances the utilization of electrons by GDY and Ag2S QDs, with the added benefit of Ag2S QDs serving as electron reservoirs for efficient photocatalytic hydrogen evolution. A 7 %Ag2S QDs/GDY composite exhibited impressive efficiency and stable performance in photocatalytic hydrogen evolution (2418 µmol g-1 h-1), which is much higher than that of GDY and Ag2S QDs. This study conclusively demonstrates that the 0D/2D heterojunction formed by GDY and Ag2S QDs can establish high-quality contact and efficient charge transfer, ultimately enhancing photocatalytic performance.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Colloid Interface Sci Año: 2024 Tipo del documento: Article Pais de publicación: Estados Unidos
Texto completo
Añadir a Mi BVS
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XML
PubMed Links
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Colloid Interface Sci Año: 2024 Tipo del documento: Article Pais de publicación: Estados Unidos