Regioselective 1,4-/1,3-Difunctionalization of 1,3-Enynes with Selenosulfonates in Water.

Deng, Hong-He; Tian, Shi-Yin; Han, Jia-Hui; Liu, Xin-Yu; Rao, Weidong; Shen, Shu-Su; Sheng, Daopeng; Yang, Zhao-Ying; Wang, Shun-Yi

Deng, Hong-He; Tian, Shi-Yin; Han, Jia-Hui; Liu, Xin-Yu; Rao, Weidong; Shen, Shu-Su; Sheng, Daopeng; Yang, Zhao-Ying; Wang, Shun-Yi.

Afiliación

Deng HH; Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.
Tian SY; Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.
Han JH; Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.
Liu XY; Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.
Rao W; Key Laboratory of Biomass-Based Green Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China.
Shen SS; School of Environmental Science and Engineering, Suzhou University of Science and Technology, No. 99, Xuefu Road, Huqiu District, Suzhou 215009, PR China.
Sheng D; Key Laboratory of Radiation Medicine and Protection, School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Soochow University, Suzhou, Jiangsu 215123, China.
Yang ZY; Soochow College, Soochow University, Suzhou 215123, China.
Wang SY; Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.

J Org Chem ; 89(12): 8804-8814, 2024 Jun 21.

Article en En | MEDLINE | ID: mdl-38860924

ABSTRACT

ABSTRACT

1,4-/1,3-Regioselective bifunctionalization of 1,3-enynes with selenosulfonates in water under catalyst-free conditions for the construction of sulfonyl allene and 1,3-disulfonyl-conjugated dienes respectively have been developed. The reactions feature mild reaction conditions in aqueous solution and remarkable regioselectivity controlled by substrates.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Org Chem Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Estados Unidos

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