Total Synthesis of Strigolactones via Palladium-Catalyzed Cascade Carbonylative Carbocyclization of Enallenes.

Yang, Bin; Federmann, Patrick; Warth, Viktoria; Ren, Mingzhe; Mu, Xin; Wu, Haibo; Bäckvall, Jan-E

Yang, Bin; Federmann, Patrick; Warth, Viktoria; Ren, Mingzhe; Mu, Xin; Wu, Haibo; Bäckvall, Jan-E.

Afiliación

Yang B; Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-10691 Stockholm, Sweden.
Federmann P; School of Chemistry, Xi'an Jiaotong University, Xi'an 710049, P. R. China.
Warth V; Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-10691 Stockholm, Sweden.
Ren M; Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-10691 Stockholm, Sweden.
Mu X; School of Chemistry, Xi'an Jiaotong University, Xi'an 710049, P. R. China.
Wu H; School of Chemistry, Xi'an Jiaotong University, Xi'an 710049, P. R. China.
Bäckvall JE; Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-10691 Stockholm, Sweden.

Org Lett ; 26(22): 4637-4642, 2024 Jun 07.

Article en En | MEDLINE | ID: mdl-38805214

ABSTRACT

ABSTRACT

Here we report an efficient route for synthesizing strigolactones (SLs) and their derivatives. Our method relies on a palladium-catalyzed oxidative carbonylation/carbocyclization/carbonylation/alkoxylation cascade reaction, which involves the formation of three new C-C bonds and a new C-O bond while cleaving one C(sp3)-H bond in a single step. With our versatile synthetic strategy, both naturally occurring and artificial SLs were prepared.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2024 Tipo del documento: Article País de afiliación: Suecia Pais de publicación: Estados Unidos

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