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Earth-Abundant Recyclable Magnetic Iron Oxide Nanoparticles for Green-light Mediated C-H Arylation in Heterogeneous Phase.
Mandal, Tanumoy; Chaturvedi, Ashwin; Azim, Aznur; Maji, Rohan; De Sarkar, Suman.
Afiliación
  • Mandal T; Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur, 741246, India.
  • Chaturvedi A; Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur, 741246, India.
  • Azim A; Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur, 741246, India.
  • Maji R; Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur, 741246, India.
  • De Sarkar S; Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur, 741246, India.
Chemistry ; 30(44): e202401617, 2024 Aug 06.
Article en En | MEDLINE | ID: mdl-38788130
ABSTRACT
A magnetically isolable iron oxide nanoparticles is introduced as an efficient heterogeneous photocatalyst for non-directed C-H arylation employing aryl diazonium salts as the aryl precursors. This first-row transition metal-based photocatalyst revealed versatile activities and is applicable to a wide range of substrates, demonstrating brilliant efficacy and superior recyclability. Detailed catalytic characterization describes the physical properties and redox behavior of the Fe-catalyst. Adequate control experiments helped to establish the radical-based mechanism for the C-H arylation.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: India Pais de publicación: Alemania

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: India Pais de publicación: Alemania