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Bias-Switchable Dual-Mode Organic Photodetector with High Operational Stability Using Self-Trapped Cs3Cu2I5 Interfacial Layer.
Zhang, Zitong; Liu, Junchuan; Wang, Lin; Wei, Qi; Li, Mingjie; Bao, Chunxiong; Bian, Qingzhen.
Afiliación
  • Zhang Z; Laboratory of Advanced Quantum Bio-optoelectronics (LAQB) State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, China.
  • Liu J; Key Laboratory of Advanced Display and System Applications of Ministry of Education, Shanghai University, Shanghai, 200072, China.
  • Wang L; Key Laboratory of Advanced Display and System Applications of Ministry of Education, Shanghai University, Shanghai, 200072, China.
  • Wei Q; Department of Applied Physics, The Hong Kong Polytechnic University, Hong Kong, 999077, China.
  • Li M; Department of Applied Physics, The Hong Kong Polytechnic University, Hong Kong, 999077, China.
  • Bao C; National Laboratory of Solid State Microstructures, School of Physics, Nanjing University, Nanjing, 210093, China.
  • Bian Q; Laboratory of Advanced Quantum Bio-optoelectronics (LAQB) State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, China.
Angew Chem Int Ed Engl ; 63(30): e202404067, 2024 Jul 22.
Article en En | MEDLINE | ID: mdl-38729916
ABSTRACT
Conventional photovoltaic (PV)-photodetectors are hard to detect fainted signals, while photomultiplication (PM)-capable devices indispensable for detecting weak light and are prone to degrade under strong light illumination and large bias, and it is urgent to realize highly efficient integrated detecting system with both PM and PV operation modes. In this work, one lead-free Cs3Cu2I5 nanocrystals with self-trapping exciton nature was introduced as interfacial layer adjacent to bulk and layer-by-layer heterojunction structure, and corresponding organic photodetectors with bias-switchable dual modes are demonstrated. The fabricated device exhibits low operating bias (0 V for PV mode and 0.8 V for PM mode), high specific detectivity (~1013 Jones), fast response speed as low as 1.59 µs, large bandwidth over 0.2 MHz and long-term operational stability last for 4 months in ambient condition. This synergy strategy also validated in different materials and device architectures, providing a convenient and scalable production process to develop highly efficient bias-switchable multi-functional organic optoelectrical applications.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Alemania

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Alemania