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Boron and Nitrogen Co-Doped Porous Graphene Nanostructures for the Electrochemical Detection of Poisonous Heavy Metal Ions.
Chaudhary, Yogesh; Suman, Shradha; Rakesh, Benadict; Ojha, Gunendra Prasad; Deshpande, Uday; Pant, Bishweshwar; Sankaran, Kamatchi Jothiramalingam.
Afiliación
  • Chaudhary Y; CSIR-Institute of Minerals and Materials Technology, Bhubaneswar 751013, India.
  • Suman S; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India.
  • Rakesh B; CSIR-Institute of Minerals and Materials Technology, Bhubaneswar 751013, India.
  • Ojha GP; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India.
  • Deshpande U; CSIR-Institute of Minerals and Materials Technology, Bhubaneswar 751013, India.
  • Pant B; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India.
  • Sankaran KJ; Carbon Composite Energy Nanomaterials Research Center, Woosuk University, Wanju 55338, Republic of Korea.
Nanomaterials (Basel) ; 14(9)2024 May 06.
Article en En | MEDLINE | ID: mdl-38727400
ABSTRACT
Heavy metal poisoning has a life-threatening impact on the human body to aquatic ecosystems. This necessitates designing a convenient green methodology for the fabrication of an electrochemical sensor that can detect heavy metal ions efficiently. In this study, boron (B) and nitrogen (N) co-doped laser-induced porous graphene (LIGBN) nanostructured electrodes were fabricated using a direct laser writing technique. The fabricated electrodes were utilised for the individual and simultaneous electrochemical detection of lead (Pb2+) and cadmium (Cd2+) ions using a square wave voltammetry technique (SWV). The synergistic effect of B and N co-doping results in an improved sensing performance of the electrode with better sensitivity of 0.725 µA/µM for Pb2+ and 0.661 µA/µM for Cd2+ ions, respectively. Moreover, the sensing electrode shows a low limit of detection of 0.21 µM and 0.25 µM for Pb2+ and Cd2+ ions, with wide linear ranges from 8.0 to 80 µM for Pb2+ and Cd2+ ions and high linearity of R2 = 0.99 in case of simultaneous detection. This rapid and facile method of fabricating heteroatom-doped porous graphene opens a new avenue in electrochemical sensing studies to detect various hazardous metal ions.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nanomaterials (Basel) Año: 2024 Tipo del documento: Article País de afiliación: India Pais de publicación: Suiza

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nanomaterials (Basel) Año: 2024 Tipo del documento: Article País de afiliación: India Pais de publicación: Suiza