Yellow-Orange Emission in Sb3+-Doped Hexakis(thiocarbamidium) Hexabromoindium(III) Tribromide.
Inorg Chem
; 63(20): 9175-9183, 2024 May 20.
Article
en En
| MEDLINE
| ID: mdl-38722294
ABSTRACT
A luminescent zero-dimensional organic-inorganic hybrid indium halide (TUH)6[In1-xSbxBr6]Br3 (TU = thiourea, 0 ≤ x ≤ 0.0998) was synthesized via the solvothermal method. In structures, resolved by single-crystal X-ray diffraction, isolated distorted [InBr6]3- and [SbBr6]3- octahedra are linked to organic TUH+ cations by intermolecular N-H···Br and N-H···S hydrogen bonds. The crystals were characterized by elemental analysis, TG-DSC, powder X-ray diffraction, FTIR analysis, and steady-state absorption and photoluminescence spectroscopy. (TUH)6[In1-xSbxBr6]Br3 exhibits a broadband yellow-orange emission centered at 595-602 nm with a half-width of 141-149 nm (0.48-0.52 eV) and a large Stokes shift of 232-238 nm (1.33-1.35 eV). This emission can be attributed to the self-trapped exciton emission of triplet states of the octahedral anion [SbBr6]3- or [InBr6]3-. Two possible emission mechanisms were discussed. Doping with Sb3+ leads to a significant increase in photoluminescence quantum yield from 25.7 at x = 0 to 48.4% at x = 0.0065, when excited at 365 nm, indicating the potential use of (TUH)6[In1-xSbxBr6]Br3 compounds in the field of photonics.
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Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Inorg Chem
Año:
2024
Tipo del documento:
Article
País de afiliación:
Rusia
Pais de publicación:
Estados Unidos