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Development and machine learning-based calibration of low-cost multiparametric stations for the measurement of CO2 and CH4 in air.
Biagi, R; Ferrari, M; Venturi, S; Sacco, M; Montegrossi, G; Tassi, F.
Afiliación
  • Biagi R; Department of Earth Sciences, University of Florence, Via G. La Pira 4, 50121, Firenze, Italy.
  • Ferrari M; Department of Earth Sciences, University of Florence, Via G. La Pira 4, 50121, Firenze, Italy.
  • Venturi S; Department of Earth Sciences, University of Florence, Via G. La Pira 4, 50121, Firenze, Italy.
  • Sacco M; Institute of Geosciences and Earth Resources (IGG), National Research Council of Italy (CNR), Via G. La Pira 4, 50121, Firenze, Italy.
  • Montegrossi G; Istituto Nazionale di Geofisica e Vulcanologia, Sezione di Palermo, Via Ugo La Malfa 153, Palermo, 90146, Italy.
  • Tassi F; Department of Physics and Astronomy, University of Florence, Via Sansone 1, 50019, Sesto Fiorentino, Firenze, Italy.
Heliyon ; 10(9): e29772, 2024 May 15.
Article en En | MEDLINE | ID: mdl-38720758
ABSTRACT
The pressing issue of atmospheric pollution has prompted the exploration of affordable methods for measuring and monitoring air contaminants as complementary techniques to standard methods, able to produce high-density data in time and space. The main challenge of this low-cost approach regards the in-field accuracy and reliability of the sensors. This study presents the development of low-cost stations for high-time resolution measurements of CO2 and CH4 concentrations calibrated via an in-field machine learning-based method. The calibration models were built based on measurements parallelly performed with the low-cost sensors and a CRDS analyzer for CO2 and CH4 as reference instrument, accounting for air temperature and relative humidity as external variables. To ensure versatility across locations, diversified datasets were collected, consisting of measurements performed in various environments and seasons. The calibration models, trained with 70 % for modeling, 15 % for validation, and 15 % for testing, demonstrated robustness with CO2 and CH4 predictions achieving R2 values from 0.8781 to 0.9827 and 0.7312 to 0.9410, and mean absolute errors ranging from 3.76 to 1.95 ppm and 0.03 to 0.01 ppm, for CO2 and CH4, respectively. These promising results pave the way for extending these stations to monitor additional air contaminants, like PM, NOx, and CO through the same calibration process, integrating them with remote data transmission modules to facilitate real-time access, control, and processing for end-users.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Heliyon Año: 2024 Tipo del documento: Article País de afiliación: Italia Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Heliyon Año: 2024 Tipo del documento: Article País de afiliación: Italia Pais de publicación: Reino Unido