Quantification of Hydride Coverage on Cu(111) by Electrochemical Mass Spectrometry.
J Phys Chem C Nanomater Interfaces
; 126(44)2022.
Article
en En
| MEDLINE
| ID: mdl-38711439
ABSTRACT
Electrochemical mass spectrometry (EC-MS) is combined with chronoamperometry to quantify H coverage associated with the surface hydride phase on Cu(111) in 0.1 mol/L H2SO4. A two-step potential pulse program is used to examine anion desorption and hydride formation, and the inverse, by tracking the 2 atomic mass unit (amu) signal for H2 production in comparison to the charge passed. On the negative potential step, the reduction current is partitioned between anion desorption, hydride formation, and the hydrogen evolution reaction (HER). For modest overpotentials, variations in partial processes are evident as inflections in the chronoamperometry and EC-MS signal. On the return step to positive potentials, hydride decomposition by H recombination to H2 occurs in parallel with sulfate adsorption. The challenge associated with the inherent diffusional delay in the EC-MS response is mitigated by total H2 collection and steady-state analysis facilitated by the thin-layer EC-MS cell geometry as demonstrated for the HER on a non-hydride forming Ag electrode. Analysis of the respective transients and steady-state response on Cu(111) reveals a saturated hydride fractional coverage of 0.67 at negative potentials with an upper bound charge of 106 µC/cm2 (average electrosorption valency of ≈1.76) associated with adsorption of the (â3×â7) mixed sulfate-water adlayer at positive potentials.
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Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
J Phys Chem C Nanomater Interfaces
Año:
2022
Tipo del documento:
Article
País de afiliación:
Estados Unidos
Pais de publicación:
Estados Unidos