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A captivating approach to elevate the detection of Al3+ ions incorporates the utilization of a tripodal receptor intricately embellishing the surface of zinc oxide.
Tamil Selvan, G; Samson, Joel; Rajasingh, P; Li, Xuesong; Ravi Kumar, A; Zhu, Nuanfei; Kuldeep, Sweety Angela; Mosae Selvakumar, Paulraj; Jun Tang, P; Zhang, Zhen.
Afiliación
  • Tamil Selvan G; School of Emergency Management, School of the Environment and Safety Engineering, Jiangsu University, Zhenjiang 212013, China.
  • Samson J; Department of NanoScience and Technology, KITS, Coimbatore, Tamil Nadu 641114, India.
  • Rajasingh P; Department of Chemistry, Kamarajar Government Arts College, Surandai, Tamil Nadu 627859, India.
  • Li X; School of Emergency Management, School of the Environment and Safety Engineering, Jiangsu University, Zhenjiang 212013, China.
  • Ravi Kumar A; School of Emergency Management, School of the Environment and Safety Engineering, Jiangsu University, Zhenjiang 212013, China.
  • Zhu N; School of Emergency Management, School of the Environment and Safety Engineering, Jiangsu University, Zhenjiang 212013, China.
  • Kuldeep SA; Environmental Science Program, Asian University for Women, Chittagong 4000, Bangladesh.
  • Mosae Selvakumar P; Environmental Science Program, Asian University for Women, Chittagong 4000, Bangladesh. Electronic address: p.selvakumar@auw.edu.bd.
  • Jun Tang P; Zhejiang Provincial Center for Disease Control and Prevention, Hangzhou 310015, China.
  • Zhang Z; School of Emergency Management, School of the Environment and Safety Engineering, Jiangsu University, Zhenjiang 212013, China. Electronic address: zhangzhen@ujs.edu.cn.
Spectrochim Acta A Mol Biomol Spectrosc ; 316: 124339, 2024 Aug 05.
Article en En | MEDLINE | ID: mdl-38696995
ABSTRACT
The FDA (Food and Drug Administration, (USA)) lists ZnO as a material that is widely acknowledged to be safe. ZnO NPs with a range of tiny particle sizes were made using the precipitation process. ZnO nanoparticles' surface is embellished with a tripodal sensor containing naphthol units. The assembly with the same receptor decorated on ZnO NPs is contrasted with the cation detection capabilities of the purified tripodal receptor. The UV-visible spectrophotometric analysis was conducted to study the state transitions of the receptor and the decorated ZnO receptor. A positive selectivity to Al3+ cations is determined by the fluorescence study under ideal circumstances. The particle size and surface morphologies are determined by DLS and SEM analysis for the same receptor - TP1 and embellished with a tripodal receptor TP2. Using a fluorescence switch-on Photoinduced Electron Transfer (PET) mechanism, the receptor coated on ZnO detects the presence of Al3+ ions with specificity. The binding constant value was determined using the B-H plot equation. Binding stoichiometry for [TP1-Al3+, TP2-Al3+] showed a 11 ratio. The fluorescence switches ON-OFF process of the ZnO surface adorned - TP2 with Tripodal receptor- TP1 was used to create molecular logic gates, which can function as a module for sensors and molecular switches. The addition of Na2EDTA in the solution of the [TP1; TP2 - Al3+] complex resulted in a noticeable reduction in the emission of fluorescence. This finding offers compelling support for the reversibility of the chemosensor. To enable the practical application of this sensor, we have developed a cassette containing receptors TP1 and TP2. Successfully, it can detect Al3+ metal ions. We performed a comprehensive assessment of the dependability and appropriateness of our approach in measuring the concentration of Al3+ ions in wastewater produced by important industrial procedures.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Spectrochim Acta A Mol Biomol Spectrosc Asunto de la revista: BIOLOGIA MOLECULAR Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Spectrochim Acta A Mol Biomol Spectrosc Asunto de la revista: BIOLOGIA MOLECULAR Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido