Triptycene-based diiron(II) mesocates: spin-crossover in solution.

Mobili, Riccardo; Preda, Giovanni; Dondi, Daniele; Monzani, Enrico; Vadivel, Dhanalakshmi; Massera, Chiara; Pasini, Dario; Amendola, Valeria

Mobili, Riccardo; Preda, Giovanni; Dondi, Daniele; Monzani, Enrico; Vadivel, Dhanalakshmi; Massera, Chiara; Pasini, Dario; Amendola, Valeria.

Afiliación

Mobili R; Department of Chemistry, University of Pavia, viale Torquato Taramelli 12, 27100 Pavia, Italy. valeria.amendola@unipv.
Preda G; Sorbonne Université, CNRS, Institut Parisien de Chimie Moléculaire, 4 Place Jussieu, Paris, France. riccardo.mobili@sorbonne-universite.fr.
Dondi D; Department of Chemistry, University of Pavia, viale Torquato Taramelli 12, 27100 Pavia, Italy. valeria.amendola@unipv.
Monzani E; Department of Chemistry, University of Pavia, viale Torquato Taramelli 12, 27100 Pavia, Italy. valeria.amendola@unipv.
Vadivel D; Department of Chemistry, University of Pavia, viale Torquato Taramelli 12, 27100 Pavia, Italy. valeria.amendola@unipv.
Massera C; Department of Chemistry, University of Pavia, viale Torquato Taramelli 12, 27100 Pavia, Italy. valeria.amendola@unipv.
Pasini D; Department of Chemistry, Life Science and Environmental Sustainability University of Parma, Parco Area delle Scienze 17/A, 43124, Parma, Italy.
Amendola V; Department of Chemistry, University of Pavia, viale Torquato Taramelli 12, 27100 Pavia, Italy. valeria.amendola@unipv.

Chem Commun (Camb) ; 60(42): 5522-5525, 2024 May 21.

Article en En | MEDLINE | ID: mdl-38695185

ABSTRACT

ABSTRACT

Triptycene-based diiron(II) and dizinc(II) mesocates were obtained using a novel rigid ligand with two pyridylbenzimidazole chelating units fused into the triptycene scaffold. Studies on the diiron(II) assembly in solution showed that the complex undergoes thermal-induced one-step spin-crossover with T1/2 at 243 K (Evans method).

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: Italia Pais de publicación: Reino Unido

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