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The determination of thallium in the environment: A review of conventional and advanced techniques and applications.
Huangfu, Xiaoliu; Zhang, Yifan; Wang, Yunzhu; Ma, Chengxue.
Afiliación
  • Huangfu X; Key Laboratory of Eco-Environments in Three Gorges Reservoir Region, Ministry of Education, College of Environment, and Ecology, Chongqing University, Chongqing 400044, China. Electronic address: hfxl-hit@163.com.
  • Zhang Y; Key Laboratory of Eco-Environments in Three Gorges Reservoir Region, Ministry of Education, College of Environment, and Ecology, Chongqing University, Chongqing 400044, China.
  • Wang Y; Key Laboratory of Eco-Environments in Three Gorges Reservoir Region, Ministry of Education, College of Environment, and Ecology, Chongqing University, Chongqing 400044, China.
  • Ma C; State Key Laboratory of Urban Water Resources and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, China.
Chemosphere ; 358: 142201, 2024 Jun.
Article en En | MEDLINE | ID: mdl-38692367
ABSTRACT
Thallium (Tl) is a potential toxicity element that poses significant ecological and environmental risks. Recently, a substantial amount of Tl has been released into the environment through natural and human activities, which attracts increasing attention. The determination of this hazardous and trace element is crucial for controlling its pollution. This article summarizes the advancement and progress in optimizing Tl detection techniques, including atomic absorption spectroscopy (AAS), voltammetry, inductively coupled plasma (ICP)-based methods, spectrophotometry, and X-ray-based methods. Additionally, it introduces sampling and pretreatment methods such as diffusive gradients in thin films (DGT), liquid-liquid extraction, solid phase extraction, and cloud point extraction. Among these techniques, ICP-mass spectrometry (MS) is the preferred choice for Tl detection due to its high precision in determining Tl as well as its species and isotopic composition. Meanwhile, some new materials and agents are employed in detection. The application of novel work electrode materials and chromogenic agents is discussed. Emphasis is placed on reducing solvent consumption and utilizing pretreatment techniques such as ultrasound-assisted processes and functionalized magnetic particles. Most detection is performed in aqueous matrices, while X-ray-based methods applied to solid phases are summarized which provide non-destructive analysis. This work improves the understanding of Tl determination technology while serving as a valuable resource for researchers seeking appropriate analytical techniques.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Talio / Monitoreo del Ambiente Idioma: En Revista: Chemosphere Año: 2024 Tipo del documento: Article Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Talio / Monitoreo del Ambiente Idioma: En Revista: Chemosphere Año: 2024 Tipo del documento: Article Pais de publicación: Reino Unido