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Copper-Catalyzed Sulfur Alkylation of Sulfenamides with N-Sulfonylhydrazones.
Han, Yidan; Yuan, Yin; Qi, Shutao; Zhang, Zhi-Kun; Kong, Xiangfei; Yang, Junfeng; Zhang, Junliang.
Afiliación
  • Han Y; College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, Guangxi 541006, People's Republic of China.
  • Yuan Y; Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai 200438, People's Republic of China.
  • Qi S; Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai 200438, People's Republic of China.
  • Zhang ZK; Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai 200438, People's Republic of China.
  • Kong X; College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, Guangxi 541006, People's Republic of China.
  • Yang J; Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai 200438, People's Republic of China.
  • Zhang J; Zhuhai Fudan Innovation Institute, Zhuhai, Guangdong 519000, People's Republic of China.
Org Lett ; 26(18): 3906-3910, 2024 May 10.
Article en En | MEDLINE | ID: mdl-38683227
ABSTRACT
Sulfilimines are valuable compounds in both organic synthesis and pharmaceuticals. In this study, we present a copper-catalyzed sulfur alkylation of sulfenamides with N-sulfonylhydrazones. In contrast to prior findings, hydrazones derived from aldehydes act as donor-type carbene precursors, effectively engaging in coupling with sulfenamides via a copper catalyst, demonstrating exclusive S selectivity. The utility of the protocol was highlighted in the rapid access to a wide range of sulfoximine derivatives.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2024 Tipo del documento: Article Pais de publicación: Estados Unidos
Texto completo
Añadir a Mi BVS
Imprimir
XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2024 Tipo del documento: Article Pais de publicación: Estados Unidos