J_{eff}=1/2 Hyperoctagon Lattice in Cobalt Oxalate Metal-Organic Framework.
Phys Rev Lett
; 132(15): 156702, 2024 Apr 12.
Article
en En
| MEDLINE
| ID: mdl-38682962
ABSTRACT
We report the magnetic properties of a cobalt oxalate metal-organic framework featuring the hyperoctagon lattice. Our thermodynamic measurements reveal the J_{eff}=1/2 state of the high-spin Co^{2+} (3d^{7}) ion and the two successive magnetic transitions at zero field with two-stage entropy release. ^{13}C-NMR measurements reveal the absence of an internal magnetic field in the intermediate temperature phase. Multiple field-induced phases are observed before full saturation at around 40 T. We argue the unique cobalt oxalate network gives rise to the Kitaev interaction and/or a bond frustration effect, providing an unconventional platform for frustrated magnetism on the hyperoctagon lattice.
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Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Phys Rev Lett
Año:
2024
Tipo del documento:
Article
País de afiliación:
Japón
Pais de publicación:
Estados Unidos