Enhanced fluoride removal using Mg-Zr binary metal oxide nanoparticles confined in a strong-base anion exchanger.
Chemosphere
; 358: 141980, 2024 Jun.
Article
en En
| MEDLINE
| ID: mdl-38670508
ABSTRACT
Generally, the pH of fluorinated groundwater or many industrial wastewater is neutral, while the majority of metal-modified adsorbents can work efficiently only under acidic conditions. In this study, we synthesized a novel hybrid adsorbent, Mg-Zr-D213, by loading nano-Mg/Zr binary metal (hydrogen) oxides in a strong-base anion exchanger, D213, to enhance the adsorption of fluoride from neutral water. Mg-Zr-D213 exhibited a better fluoride-removal capacity in neutral water than monometallic modified resins. Under the interference of competing anions and coexisting organic acids, Mg-Zr-D213 exhibited superior selectivity. The Langmuir model indicated that the fitted maximum sorption capacity of Mg-Zr-D213 was 41.38 mg/g. The results of column experiments showed that the effective treatment volume of Mg-Zr-D213 was 8-16-times higher than that of D213 for both synthetic groundwater and actual industrial wastewater, and that NaOH-NaCl eluent could effectively recover more than 95% of fluoride. Adsorption experiments with Mg/Zr metal (hydrogen) oxide particles and D213 separately demonstrated a synergistic effect between -N+(CH3)3 and Mg/Zr metal (hydrogen) oxide particles. The ligand exchange or metal-ligand interaction of Mg/Zr metal (hydrogen) oxide particles on fluoride was further demonstrated via X-ray photoelectron spectroscopy. Overall, Mg-Zr-D213 has great potential for enhanced fluoride removal in neutral water.
Palabras clave
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Contaminantes Químicos del Agua
/
Circonio
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Agua Subterránea
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Purificación del Agua
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Nanopartículas del Metal
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Fluoruros
Idioma:
En
Revista:
Chemosphere
Año:
2024
Tipo del documento:
Article
País de afiliación:
China
Pais de publicación:
Reino Unido