10-Phenylphenothiazine-Organophotocatalyzed Bromo-Perfluoroalkylation of Unactivated Olefins.

Tagami, Koto; Nakayama, Moeko; Kanbara, Tadashi; Cahard, Dominique; Yajima, Tomoko

Tagami, Koto; Nakayama, Moeko; Kanbara, Tadashi; Cahard, Dominique; Yajima, Tomoko.

Afiliación

Tagami K; Department of Chemistry, Ochanomizu University, Tokyo 112-8610, Japan.
Nakayama M; CNRS, UMR 6014 COBRA, Univ Rouen Normandie, INSA Rouen, Normandie Univ, INC3M FR 3038, F-76000 Rouen, France.
Kanbara T; Department of Chemistry, Ochanomizu University, Tokyo 112-8610, Japan.
Cahard D; Department of Chemistry, Ochanomizu University, Tokyo 112-8610, Japan.
Yajima T; CNRS, UMR 6014 COBRA, Univ Rouen Normandie, INSA Rouen, Normandie Univ, INC3M FR 3038, F-76000 Rouen, France.

J Org Chem ; 89(10): 7084-7094, 2024 May 17.

Article en En | MEDLINE | ID: mdl-38663869

ABSTRACT

ABSTRACT

In this study, we have developed a smooth metal-free visible-light-induced bromo-perfluoroalkylation of unactivated olefins with the aid of 10-phenylphenothiazine (PTH) as an organic photoredox catalyst. The reaction is 100% atom-economic redox-neutral and proceeds with stoichiometric amounts of olefin and perfluoroalkyl bromide. To show the potential of these unexplored motifs, we carried out various postfunctionalizations taking advantage of the bromine atom, including gram-scale experiments.

Texto completo

Añadir a Mi BVS

Imprimir

XML

PubMed Links

Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Org Chem Año: 2024 Tipo del documento: Article País de afiliación: Japón Pais de publicación: Estados Unidos

Texto completo

Añadir a Mi BVS

Imprimir

XML

PubMed Links

Buscar en Google