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Enhanced bioelectroremediation of heavy metal contaminated groundwater through advancing a self-standing cathode.
Ali, Jafar; Zheng, Changhong; Lyu, Tao; Oladoja, Nurudeen Abiola; Lu, Ying; An, Wengang; Yang, Yuesuo.
Afiliación
  • Ali J; Key Lab of Groundwater Resources and Environment (Jilin University), Ministry of Education, Changchun 130021, China; Jilin Provincial Key Laboratory of Water Resources and Environment, Jilin University, Changchun 130021, China.
  • Zheng C; Key Lab of Groundwater Resources and Environment (Jilin University), Ministry of Education, Changchun 130021, China; Jilin Provincial Key Laboratory of Water Resources and Environment, Jilin University, Changchun 130021, China.
  • Lyu T; School of Water, Energy and Environment, Cranfield University, College Road, Bedfordshire MK43 0AL, UK. Electronic address: t.lyu@cranfield.ac.uk.
  • Oladoja NA; Hydrochemistry Research Laboratory, Department of Chemical Sciences, Adekunle Ajasin University, Akungba Akoko, Nigeria.
  • Lu Y; Key Lab of Groundwater Resources and Environment (Jilin University), Ministry of Education, Changchun 130021, China; Jilin Provincial Key Laboratory of Water Resources and Environment, Jilin University, Changchun 130021, China.
  • An W; Key Lab of Groundwater Resources and Environment (Jilin University), Ministry of Education, Changchun 130021, China; Jilin Provincial Key Laboratory of Water Resources and Environment, Jilin University, Changchun 130021, China.
  • Yang Y; Key Lab of Groundwater Resources and Environment (Jilin University), Ministry of Education, Changchun 130021, China; Jilin Provincial Key Laboratory of Water Resources and Environment, Jilin University, Changchun 130021, China. Electronic address: yangyuesuo@jlu.edu.cn.
Water Res ; 256: 121625, 2024 Jun 01.
Article en En | MEDLINE | ID: mdl-38640565
ABSTRACT
Hexavalent chromium (Cr(VI)) contamination in groundwater poses a substantial global challenge due to its high toxicity and extensive industrial applications. While the bioelectroremediation of Cr(VI) has attracted huge attention for its eco-friendly attributes, its practical application remains constrained by the hydrogeochemical conditions of groundwater (mainly pH), low electron transfer efficiency, limitations in electrocatalyst synthesis and electrode fabrication. In this study, we developed and investigated the use of N, S co-doped carbon nanofibers (CNFs) integrated on a graphite felt (GF) as a self-standing cathode (NS/CNF-GF) for the comprehensive reduction of Cr(VI) from real contaminated groundwater. The binder free cathode, prepared through electro-polymerization, was employed in a dual-chamber microbial fuel cell (MFC) for the treatment of Cr (VI)-laden real groundwater (40 mg/L) with a pH of 7.4. The electrochemical characterization of the prepared cathode revealed a distinct electroactive surface area, more wettability, facilitating enhanced adsorption and rapid electron transfer, resulting in a commendable Cr(VI) reduction rate of 0.83 mg/L/h. The MFC equipped with NS/CNF-GF demonstrated the lowest charge transfer resistance (Rct) and generated the highest power density (155 ± 0.3 mW/m2) compared to control systems. The favorable electrokinetics for modified cathode led to swift substrate consumption in the anode, releasing more electrons and protons, thereby accelerating Cr(VI) reduction to achieve the highest cathodic coulombic efficiency (C.Eca)of80 ± 1.3 %. A similar temporal trend observed between Cr(VI) removal efficiency, COD removal efficiency, and C.Eca, underscores the effective performance of the modified electrode. The reusability of the binder free cathode, exemption from catholyte preparation and the absence of pH regulation requirements highlighted the potential scalability and applicability of our findings on a larger scale.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Contaminantes Químicos del Agua / Agua Subterránea / Cromo / Electrodos Idioma: En Revista: Water Res Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Contaminantes Químicos del Agua / Agua Subterránea / Cromo / Electrodos Idioma: En Revista: Water Res Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido