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Enhancing the Tribological Properties of Low-Density Polyethylene Using Hard Carbon Microfillers.
Solomon, Samuel; Hall, Rachel; He, Jibao; John, Vijay; Pesika, Noshir.
Afiliación
  • Solomon S; Department of Chemical and Biomolecular Engineering, Tulane University, 6823 St. Charles Ave., New Orleans, LA 70118, USA.
  • Hall R; New Product Development, Intralox LLC, 301 Plantation Rd., New Orleans, LA 70123, USA.
  • He J; Microscopy Laboratory, Tulane University, New Orleans, LA 70118, USA.
  • John V; Department of Chemical and Biomolecular Engineering, Tulane University, 6823 St. Charles Ave., New Orleans, LA 70118, USA.
  • Pesika N; Department of Chemical and Biomolecular Engineering, Tulane University, 6823 St. Charles Ave., New Orleans, LA 70118, USA.
Materials (Basel) ; 17(7)2024 Mar 28.
Article en En | MEDLINE | ID: mdl-38612054
ABSTRACT
The application of low-density polyethylene (LDPE) has been confined to packaging applications due to its inadequate mechanical and tribological characteristics. We propose enhancing LDPE by integrating hard carbon spheres (CSs) to improve its strength, frictional characteristics, and wear resistance. LDPE/CS composites were created by blending LDPE with varying CS amounts (0.5-8 wt.%). Analysis using scanning electron microscopy and Raman spectroscopy confirmed CS presence in the LDPE matrix, with X-ray diffraction showing no microstructural changes post-blending. Thermal characterization exhibited notable improvements in thermal stability (~4%) and crystallinity (~7%). Mechanical properties such as hardness and Young's modulus were improved by up to 4% and 24%, respectively. Tribological studies on different composite samples with varying surface roughness under various load and speed conditions revealed the critical role of surface roughness in reducing friction by decreasing real contact area and adhesive interactions between asperities. Increased load and speed amplified shear stress on asperities, possibly leading to deformation and failure. Notably, integrating CSs into LDPE, starting at 1 wt.%, effectively reduced friction and wear. The composite with the highest loading (8 wt.%) displayed the most significant tribological enhancement, achieving a remarkable 75% friction reduction and a substantial 78% wear reduction.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Materials (Basel) Año: 2024 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Suiza

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Materials (Basel) Año: 2024 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Suiza