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Crystal structure of defect scheelite-type Nd2/3[WO4].
Knies, Benjamin; Hartenbach, Ingo.
Afiliación
  • Knies B; University of Stuttgart, Institute of Inorganic Chemistry, Pfaffenwaldring 55, 70569 Stuttgart, Germany.
  • Hartenbach I; University of Stuttgart, Institute of Inorganic Chemistry, Pfaffenwaldring 55, 70569 Stuttgart, Germany.
IUCrdata ; 9(Pt 3): x240175, 2024 Mar.
Article en En | MEDLINE | ID: mdl-38586517
ABSTRACT
Neodymium(III) ortho-oxidotungstate(VI) was synthesized as a side-product in an unsuccessful synthesis attempt at fluoride derivatives of neodymium tungstate in fused silica ampoules, using neodymium(III) oxide, neodymium(III) fluoride and tungsten trioxide. Violet, platelet-shaped single crystals of the title compound emerged of the bulk, which crystallize in the defect scheelite type with a trigonal dodeca-hedral coordination of oxide anions around the Nd3+ cations and the hexa-valent tungsten cations situated in the centers of oxide tetra-hedra.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: IUCrdata Año: 2024 Tipo del documento: Article País de afiliación: Alemania Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: IUCrdata Año: 2024 Tipo del documento: Article País de afiliación: Alemania Pais de publicación: Reino Unido