Your browser doesn't support javascript.
loading
Formoxyboranes as hydroborane surrogates for the catalytic reduction of carbonyls through transfer hydroboration.
Durin, Gabriel; Romero, R Martin; Godou, Timothé; Chauvier, Clément; Thuéry, Pierre; Nicolas, Emmanuel; Cantat, Thibault.
Afiliación
  • Durin G; NIMBE, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191 Gif-sur-Yvette Cedex France thibault.cantat@cea.fr.
  • Romero RM; NIMBE, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191 Gif-sur-Yvette Cedex France thibault.cantat@cea.fr.
  • Godou T; NIMBE, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191 Gif-sur-Yvette Cedex France thibault.cantat@cea.fr.
  • Chauvier C; NIMBE, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191 Gif-sur-Yvette Cedex France thibault.cantat@cea.fr.
  • Thuéry P; NIMBE, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191 Gif-sur-Yvette Cedex France thibault.cantat@cea.fr.
  • Nicolas E; NIMBE, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191 Gif-sur-Yvette Cedex France thibault.cantat@cea.fr.
  • Cantat T; NIMBE, CEA, CNRS, Université Paris-Saclay, CEA Saclay 91191 Gif-sur-Yvette Cedex France thibault.cantat@cea.fr.
Catal Sci Technol ; 14(7): 1848-1853, 2024 Apr 02.
Article en En | MEDLINE | ID: mdl-38571548
ABSTRACT
A new class of Lewis base stabilized formoxyboranes demonstrates the feasibility of catalytic transfer hydroboration. In the presence of a ruthenium catalyst, they have shown broad applicability for reducing carbonyl compounds. Various borylated alcohols are obtained in high selectivity and yields up to 99%, tolerating several functional groups. Computational studies enabled to propose a mechanism for this transformation, revealing the role of the ruthenium catalyst and the absence of hydroborane intermediates.
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Catal Sci Technol Año: 2024 Tipo del documento: Article Pais de publicación: Reino Unido
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Catal Sci Technol Año: 2024 Tipo del documento: Article Pais de publicación: Reino Unido