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A novel micellular fluorogenic substrate for quantitating the activity of 1-phosphatidylinositol 4,5-bisphosphate phosphodiesterase gamma (PLCγ) enzymes.
Visvanathan, Ramya; Utsuki, Tadanobu; Beck, Daniel E; Clayton, W Brent; Lendy, Emma; Sun, Kuai-Lin; Liu, Yinghui; Hering, Kirk W; Mesecar, Andrew; Zhang, Zhong-Yin; Putt, Karson S.
Afiliación
  • Visvanathan R; Institute for Drug Discovery, Purdue University, West Lafayette, IN, United States of America.
  • Utsuki T; IUSM-Purdue TREAT-AD Center, West Lafayette, IN, United States of America.
  • Beck DE; Department of Medicinal Chemistry and Molecular Pharmacology, Purdue University, West Lafayette, IN, United States of America.
  • Clayton WB; Institute for Drug Discovery, Purdue University, West Lafayette, IN, United States of America.
  • Lendy E; IUSM-Purdue TREAT-AD Center, West Lafayette, IN, United States of America.
  • Sun KL; Institute for Drug Discovery, Purdue University, West Lafayette, IN, United States of America.
  • Liu Y; IUSM-Purdue TREAT-AD Center, West Lafayette, IN, United States of America.
  • Hering KW; IUSM-Purdue TREAT-AD Center, West Lafayette, IN, United States of America.
  • Mesecar A; Division of Clinical Pharmacology, Indiana University School of Medicine, Indianapolis, IN, United States of America.
  • Zhang ZY; IUSM-Purdue TREAT-AD Center, West Lafayette, IN, United States of America.
  • Putt KS; Department of Biochemistry, Purdue University, West Lafayette, IN, United States of America.
PLoS One ; 19(3): e0299541, 2024.
Article en En | MEDLINE | ID: mdl-38551930
ABSTRACT
The activities of the phospholipase C gamma (PLCγ) 1 and 2 enzymes are essential for numerous cellular processes. Unsurprisingly, dysregulation of PLCγ1 or PLCγ2 activity is associated with multiple maladies including immune disorders, cancers, and neurodegenerative diseases. Therefore, the modulation of either of these two enzymes has been suggested as a therapeutic strategy to combat these diseases. To aid in the discovery of PLCγ family enzyme modulators that could be developed into therapeutic agents, we have synthesized a high-throughput screening-amenable micellular fluorogenic substrate called C16CF3-coumarin. Herein, the ability of PLCγ1 and PLCγ2 to enzymatically process C16CF3-coumarin was confirmed, the micellular assay conditions were optimized, and the kinetics of the reaction were determined. A proof-of-principle pilot screen of the Library of Pharmacologically Active Compounds 1280 (LOPAC1280) was performed. This new substrate allows for an additional screening methodology to identify modulators of the PLCγ family of enzymes.
Asunto(s)

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Fosfatidilinositoles / Colorantes Fluorescentes Idioma: En Revista: PLoS One Asunto de la revista: CIENCIA / MEDICINA Año: 2024 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Fosfatidilinositoles / Colorantes Fluorescentes Idioma: En Revista: PLoS One Asunto de la revista: CIENCIA / MEDICINA Año: 2024 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos