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Regulating Electrolyte Solvation Structures via Diluent-Solvent Interactions for Safe High-Voltage Lithium Metal Batteries.
Liu, Yuqi; Li, Jin; Deng, Xiaolan; Chi, Shang-Sen; Wang, Jun; Zeng, Huipeng; Jiang, Yidong; Li, Tingting; Liu, Zhongbo; Wang, Hui; Zhang, Guangzhao; Deng, Yonghong; Wang, Chaoyang.
Afiliación
  • Liu Y; Research Institute of Materials Science, South China University of Technology, Guangzhou, 510640, China.
  • Li J; Research & Development Center, GAC Aion New Energy Automobile Co., Ltd., Guangzhou, 510640, China.
  • Deng X; Zen Semiconductor Corporation, Guangzhou, 510000, China.
  • Chi SS; Department of Materials Science & Engineering, Southern University of Science and Technology, Shenzhen, 518055, China.
  • Wang J; Department of Materials Science & Engineering, Southern University of Science and Technology, Shenzhen, 518055, China.
  • Zeng H; Department of Materials Science & Engineering, Southern University of Science and Technology, Shenzhen, 518055, China.
  • Jiang Y; Research Institute of Materials Science, South China University of Technology, Guangzhou, 510640, China.
  • Li T; ZTE Plaza, Keji Road South, Hi-Tech Industrial Park, Nanshan, Shenzhen, 518057, China.
  • Liu Z; Shenzhen CAPCHEM Technology Co. Ltd., Shenzhen, 518118, China.
  • Wang H; Research Institute of Materials Science, South China University of Technology, Guangzhou, 510640, China.
  • Zhang G; Research Institute of Materials Science, South China University of Technology, Guangzhou, 510640, China.
  • Deng Y; Department of Materials Science & Engineering, Southern University of Science and Technology, Shenzhen, 518055, China.
  • Wang C; Key Laboratory of Polymer Processing Engineering (South China University of Technology), Ministration of Education, Guangzhou, 510640, China.
Small ; 20(31): e2311812, 2024 Aug.
Article en En | MEDLINE | ID: mdl-38453675
ABSTRACT
Local high concentration electrolytes (LHCEs) have been proved to be one of the most promising systems to stabilize both high voltage cathodes and Li metal anode for next-generation batteries. However, the solvation structures and interactions among different species in LHCEs are still convoluted, which bottlenecks the further breakthrough on electrolyte development. Here, it is demonstrated that the hydrogen bonding interaction between diluent and solvent is crucial for the construction of LHCEs and corresponding interphase chemistries. The 2,2,2-trifluoroethyl trifluoromethane sulfonate (TFSF) is selected as diluent with the solvent dimethoxy-ethane (DME) to prepare a non-flammable LHCE for high voltage LMBs. This is first find that the hydrogen bonding interaction between TFSF and DME solvent tailors the electrolyte solvation structures by weakening the coordination of DME molecules to Li+ cations and allows more participation of anions in the first solvation shell, leading to the formation of aggregates (AGGs) clusters which are conducive to generating inorganic solid/cathodic electrolyte interphases (SEI/CEIs). The proposed TFSF based LHCE enables the Li||NCM811 (LiNi0.8Mn0.1O2) batteries to realize >80% capacity retention with a high average Coulombic efficiency of 99.8% for 230 cycles under aggressive conditions (NCM811 cathode 3.4 mAh cm-2, cut-off voltage 4.4 V, and 20 µm Li foil).
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Small Asunto de la revista: ENGENHARIA BIOMEDICA Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Alemania
Texto completo
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XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Small Asunto de la revista: ENGENHARIA BIOMEDICA Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Alemania