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Oxygen quenching of structurally characterized [5,10,15,20-tetrakis(4-fluoro-2,6-dimethylphenyl)porphyrinato]platinum(II).
Dash, Zane S; Huang, Raymond Q; Kimber, Ana N; Olubajo, Opeyemi T; Polk, Mark; Rancu, Oliver P; Zhang, Lauren L; Fu, Jane; Nagelj, Nejc; Reynolds, Kristopher G; Zheng, Shao Liang; Dogutan, Dilek K.
Afiliación
  • Dash ZS; Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA.
  • Huang RQ; Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA.
  • Kimber AN; Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA.
  • Olubajo OT; Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA.
  • Polk M; Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA.
  • Rancu OP; Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA.
  • Zhang LL; Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA.
  • Fu J; Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA.
  • Nagelj N; Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA.
  • Reynolds KG; Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA.
  • Zheng SL; Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA.
  • Dogutan DK; Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA.
Acta Crystallogr C Struct Chem ; 80(Pt 3): 85-90, 2024 Mar 01.
Article en En | MEDLINE | ID: mdl-38407217
ABSTRACT
The compound [5,10,15,20-tetrakis(4-fluoro-2,6-dimethylphenyl)porphyrinato]platinum(II), [Pt(C52H40F4N4)] or Pt(II)TFP, has been synthesized and structurally characterized by single-crystal X-ray crystallography. The Pt porphyrin exhibits a long-lived phosphorescent excited state (τ0 = 66 µs), which has been characterized by transient absorption and emission spectroscopy. The phosphorescence is extremely sensitive to oxygen, as reflected by a quenching rate constant of 5.0 × 108 M-1 s-1, and as measured by Stern-Volmer quenching analysis.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Acta Crystallogr C Struct Chem Año: 2024 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Reino Unido
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Acta Crystallogr C Struct Chem Año: 2024 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Reino Unido