New insights into tunnel-type NaxMnO2-yFy with high performance and excellent cycling stability: the impact of F-doping.
Dalton Trans
; 53(10): 4814-4822, 2024 Mar 05.
Article
en En
| MEDLINE
| ID: mdl-38372570
ABSTRACT
Developing sustainable batteries based on abundant elements such as sodium and manganese is very attractive. Thus, sodium-manganese oxides can be employed as electrodes for sodium-ion batteries. Herein, an NaxMnO2-yFy electrode material is investigated and optimized. Galvanostatic cycling and diffusion coefficient calculations have been employed. It is found that tailoring the stoichiometry using the sodium/manganese ratio and fluorine content in the synthesis can improve the electrochemical performance and achieve high capacity and superb cycling stability. An anion-doping strategy (F-doping) can significantly improve electrode stability, and greatly raise the maximum specific capacity from ca. 70 mA h g-1 for an F-free sample to ca. 120 mA h g-1 for an F-doped sample at a slow rate (10 mA g-1 of current intensity). The reversible capacity of the F-doped sample is stable for many cycles (around 40-45 mA h g-1 at 500 mA g-1 for 1000 cycles).
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Dalton Trans
Asunto de la revista:
QUIMICA
Año:
2024
Tipo del documento:
Article
País de afiliación:
España
Pais de publicación:
Reino Unido