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Toward Producing Biopolyethylene/Babassu Fiber Biocomposites with Improved Mechanical and Thermomechanical Properties.
Ferreira, Eduardo da Silva Barbosa; da Silva, Fabiano Santana; Luna, Carlos Bruno Barreto; Costa, Anna Raffaela de Matos; de Sousa, Fernanda Menezes; de Carvalho, Laura Hecker; Wellen, Renate Maria Ramos; Araújo, Edcleide Maria.
Afiliación
  • Ferreira EDSB; Department of Materials Engineering, Federal University of Campina Grande, Campina Grande 58429-900, PB, Brazil.
  • da Silva FS; Department of Materials Engineering, Federal University of Campina Grande, Campina Grande 58429-900, PB, Brazil.
  • Luna CBB; Department of Materials Engineering, Federal University of Campina Grande, Campina Grande 58429-900, PB, Brazil.
  • Costa ARM; CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal.
  • de Sousa FM; Department of Materials Engineering, Federal University of Campina Grande, Campina Grande 58429-900, PB, Brazil.
  • de Carvalho LH; Department of Materials Engineering, Federal University of Campina Grande, Campina Grande 58429-900, PB, Brazil.
  • Wellen RMR; Department of Materials Engineering, Federal University of Paraíba, João Pessoa 58051-900, PB, Brazil.
  • Araújo EM; Department of Materials Engineering, Federal University of Campina Grande, Campina Grande 58429-900, PB, Brazil.
Polymers (Basel) ; 16(3)2024 Feb 02.
Article en En | MEDLINE | ID: mdl-38337308
ABSTRACT
The development of polymeric biocomposites containing natural fibers has grown over the years due to the properties achieved and its eco-friendly nature. Thus, biocomposites involving a polymer from a renewable source (Biopolyethylene (BioPE)) and babassu fibers (BFs), compatibilized with polyethylene grafted with maleic anhydride (MA) and acrylic acid (AA) (PE-g-MA and PE-g-AA, respectively) were obtained using melt mixing and injection molded into tensile, impact, and HDT specimens. Babassu fiber was characterized with Fourier transform infrared spectroscopy (FTIR), thermogravimetry (TGA), and scanning electron microscopy (SEM). The biocomposites were characterized using torque rheometry, TGA, tensile strength, impact strength, thermomechanical properties, Shore D hardness, and SEM. The data indicate that the torque during the processing of compatibilized biocomposites was higher than that of BioPE/BF biocomposites, which was taken as an indication of a possible reaction between the functional groups. Compatibilization led to a substantial improvement in the elastic modulus, tensile strength, HDT, and VST and a decrease in Shore D hardness. These results were justified with SEM micrographs, which showed babassu fibers better adhered to the surface of the biopolyethylene matrix, as well as an encapsulation of these fibers. The system investigated is environmentally sustainable, and the results are promising for the technology of polymeric composites.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Polymers (Basel) Año: 2024 Tipo del documento: Article País de afiliación: Brasil Pais de publicación: Suiza

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Polymers (Basel) Año: 2024 Tipo del documento: Article País de afiliación: Brasil Pais de publicación: Suiza