Design of a high-temperature cell for cobalt-60 irradiations of aqueous solutions with in situ UV-visible spectroscopy.
Rev Sci Instrum
; 95(2)2024 Feb 01.
Article
en En
| MEDLINE
| ID: mdl-38310638
ABSTRACT
To understand the speciation of solutes in aqueous solutions in high temperature radiation environments, we report the design and fabrication of a custom-built, high temperature (≤300 °C) titanium irradiation cell with in situ optical spectroscopy capabilities, as afforded by coupled fiber optic cables. The wetted surfaces of the 8-inch tall cylindrical cell with 3.5 in. diameter are entirely made of titanium, sapphire, and gold, which are chemically and radiolytically inert. The initial benchmarking results are reported, including the baseline spectrum of deionized water as a function of temperature, the stability of a spectrum over 4 h at 100 °C, and an irradiated Fricke dosimetry solution under ambient irradiator temperature conditions (27.0 ± 0.5 °C). The average gamma radiation dose rate in the cell in its current configuration is 26.1 ± 1.3 Gy min-1. This cell has application in studying several processes throughout the nuclear fuel cycle, including the reactor coolant behavior.
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01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Rev Sci Instrum
Año:
2024
Tipo del documento:
Article
País de afiliación:
Estados Unidos
Pais de publicación:
Estados Unidos