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Carbon-reinforced Ni3S2/Ti3C2Tx MXene composite as an anode for superior-performance lithium-ion capacitors.
Deng, Xu-Geng; Fan, Le-Qing; Fu, Xiao-Yun; Tang, Tao; Lin, Shi-Hua; Chen, Long; Yu, Fu-Da; Huang, Yun-Fang; Huang, Miao-Liang; Wu, Ji-Huai.
Afiliación
  • Deng XG; Fujian Key Laboratory of Photoelectric Functional Materials, College of Materials Science and Engineering, Huaqiao University, Xiamen, Fujian 361021, China; Engineering Research Center of Environment-Friendly Functional Materials, Ministry of Education, Huaqiao University, Xiamen, Fujian 361021, Chi
  • Fan LQ; Fujian Key Laboratory of Photoelectric Functional Materials, College of Materials Science and Engineering, Huaqiao University, Xiamen, Fujian 361021, China; Engineering Research Center of Environment-Friendly Functional Materials, Ministry of Education, Huaqiao University, Xiamen, Fujian 361021, Chi
  • Fu XY; Fujian Key Laboratory of Photoelectric Functional Materials, College of Materials Science and Engineering, Huaqiao University, Xiamen, Fujian 361021, China; Engineering Research Center of Environment-Friendly Functional Materials, Ministry of Education, Huaqiao University, Xiamen, Fujian 361021, Chi
  • Tang T; Fujian Key Laboratory of Photoelectric Functional Materials, College of Materials Science and Engineering, Huaqiao University, Xiamen, Fujian 361021, China; Engineering Research Center of Environment-Friendly Functional Materials, Ministry of Education, Huaqiao University, Xiamen, Fujian 361021, Chi
  • Lin SH; Fujian Key Laboratory of Photoelectric Functional Materials, College of Materials Science and Engineering, Huaqiao University, Xiamen, Fujian 361021, China; Engineering Research Center of Environment-Friendly Functional Materials, Ministry of Education, Huaqiao University, Xiamen, Fujian 361021, Chi
  • Chen L; Fujian Key Laboratory of Photoelectric Functional Materials, College of Materials Science and Engineering, Huaqiao University, Xiamen, Fujian 361021, China; Engineering Research Center of Environment-Friendly Functional Materials, Ministry of Education, Huaqiao University, Xiamen, Fujian 361021, Chi
  • Yu FD; Fujian Key Laboratory of Photoelectric Functional Materials, College of Materials Science and Engineering, Huaqiao University, Xiamen, Fujian 361021, China; Engineering Research Center of Environment-Friendly Functional Materials, Ministry of Education, Huaqiao University, Xiamen, Fujian 361021, Chi
  • Huang YF; Engineering Research Center of Environment-Friendly Functional Materials, Ministry of Education, Huaqiao University, Xiamen, Fujian 361021, China.
  • Huang ML; Fujian Key Laboratory of Photoelectric Functional Materials, College of Materials Science and Engineering, Huaqiao University, Xiamen, Fujian 361021, China; Engineering Research Center of Environment-Friendly Functional Materials, Ministry of Education, Huaqiao University, Xiamen, Fujian 361021, Chi
  • Wu JH; Fujian Key Laboratory of Photoelectric Functional Materials, College of Materials Science and Engineering, Huaqiao University, Xiamen, Fujian 361021, China; Engineering Research Center of Environment-Friendly Functional Materials, Ministry of Education, Huaqiao University, Xiamen, Fujian 361021, Chi
J Colloid Interface Sci ; 661: 237-248, 2024 May.
Article en En | MEDLINE | ID: mdl-38301462
ABSTRACT
Lithium ion capacitors (LICs) are a new generation of energy storage devices that combine the super energy storage capability of lithium ion batteries with the satisfactory power density of supercapacitors. The development of high-performance LICs still faces great challenges due to the unbalanced reaction kinetics at the anode and cathode. Therefore, it is an inevitable need to enhance the electron/ion transfer capability of the anode materials. In this paper, to obtain a superior-rate and high-capacity Ni3S2-based anode, highly conductive Ti3C2Tx MXene sheets were introduced to sever as the carrier of Ni3S2 nanoparticles and simultaneously an amorphous carbon layer which coats onto the surface of Ni3S2 nanoparticles was in-situ generated by the carbonization of dopamine reactant. The as-synthesized Ni3S2/Ti3C2Tx/C composite exhibits a high specific surface area (112.6 m2/g) because of the addition of Ti3C2Tx that can reduce the aggregation of Ni3S2 nanoparticles and the in-situ generated amorphous carbon layer that can suppress the growth of Ni3S2 nanoparticles. The Ni3S2/Ti3C2Tx/C anode possesses a remarkable reversible discharge specific capacity (626.0 mAh/g under 0.2 A/g current density), which increases to 1150.8 mAh/g after 400-cycle charge/discharge measurement at the same measurement condition indicating eminent cyclability, along with superior rate capability. To construct a superior-performance LIC device, a sterculiae lychnophorae derived porous carbon (SLPC) cathode with an average discharge specific capacity of 73.4 mAh/g@0.1A/g was prepared. The Ni3S2/Ti3C2Tx/C//SLPC LIC device with optimal cathode/anode mass ratio has a satisfactory energy density ranging from 32.8 to 119.1 Wh kg-1 at the corresponding power density of 8799.4 to 157.5 W kg-1, together with a prominent capacity retention (95.5 %@1 A/g after 10,000 cycles).
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Colloid Interface Sci Año: 2024 Tipo del documento: Article Pais de publicación: Estados Unidos
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Colloid Interface Sci Año: 2024 Tipo del documento: Article Pais de publicación: Estados Unidos