Regioselective Diels-Alder Reactions of Anthracenes with Olefins via Visible Light Photocatalysis in a Homogeneous Solution.

Zhou, Chao; Liu, Zan; Liang, Ge; Zhang, Ya-Qiong; Lei, Tao; Chen, Bin; Liao, Rong-Zhen; Tung, Chen-Ho; Wu, Li-Zhu

Zhou, Chao; Liu, Zan; Liang, Ge; Zhang, Ya-Qiong; Lei, Tao; Chen, Bin; Liao, Rong-Zhen; Tung, Chen-Ho; Wu, Li-Zhu.

Afiliación

Zhou C; Key Laboratory of Photochemical Conversion and Optoelectronic Materials, New Cornerstone Science Laboratory, Technical Institute of Physics and Chemistry, The Chinese Academy of Sciences, Beijing 100190, PR China.
Liu Z; School of Future Technology, University of Chinese Academy of Sciences, Beijing 100049, PR China.
Liang G; Key Laboratory of Photochemical Conversion and Optoelectronic Materials, New Cornerstone Science Laboratory, Technical Institute of Physics and Chemistry, The Chinese Academy of Sciences, Beijing 100190, PR China.
Zhang YQ; School of Future Technology, University of Chinese Academy of Sciences, Beijing 100049, PR China.
Lei T; Key Laboratory of Photochemical Conversion and Optoelectronic Materials, New Cornerstone Science Laboratory, Technical Institute of Physics and Chemistry, The Chinese Academy of Sciences, Beijing 100190, PR China.
Chen B; School of Future Technology, University of Chinese Academy of Sciences, Beijing 100049, PR China.
Liao RZ; School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China.
Tung CH; Key Laboratory of Photochemical Conversion and Optoelectronic Materials, New Cornerstone Science Laboratory, Technical Institute of Physics and Chemistry, The Chinese Academy of Sciences, Beijing 100190, PR China.
Wu LZ; School of Future Technology, University of Chinese Academy of Sciences, Beijing 100049, PR China.

Org Lett ; 26(5): 1116-1121, 2024 Feb 09.

Article en En | MEDLINE | ID: mdl-38295357

ABSTRACT

ABSTRACT

Diels-Alder cycloaddition of anthracene with olefin is achieved in a homogeneous solution via energy transfer under visible light. A series of substrates including electroneutral styrene derivatives can be successfully converted into the corresponding cycloadducts in a head-to-head orientation with high to excellent yields. The high ortho-regioselectivity, mild condition, and broad substrate scope enable promising advances in organic transformation.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2024 Tipo del documento: Article Pais de publicación: Estados Unidos

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