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Structural, Optical, and Magnetic Properties of Pure and Ni-Fe-Codoped Zinc Oxide Nanoparticles Synthesized by a Sol-Gel Autocombustion Method.
Ahmed, Nasar; Khalil, Zakia; Farooq, Zahid; Shahida, Shabnam; Ahmad, Pervaiz; Qadir, Karwan Wasman; Khan, Rajwali; Zafar, Qayyum.
Afiliación
  • Ahmed N; Department of Physics, King Abdullah Campus, University of Azad Jammu and Kashmir, Muzaffarabad 13100, Pakistan.
  • Khalil Z; Department of Physics, Mirpur University of Science and Technology, Muzaffarabad, Azad Jammu and Kashmir 10250, Pakistan.
  • Farooq Z; Department of Physics, Division of Science and Technology, University of Education, Lahore 54000, Pakistan.
  • Khizar-Ul-Haq; Department of Physics, Mirpur University of Science and Technology, Muzaffarabad, Azad Jammu and Kashmir 10250, Pakistan.
  • Shahida S; Department of Chemistry, University of Poonch, Rawalakot, Azad Kashmir 12350, Pakistan.
  • Ramiza; Department of Physics, University of Agriculture, Faisalabad 38000, Pakistan.
  • Ahmad P; Department of Physics, King Abdullah Campus, University of Azad Jammu and Kashmir, Muzaffarabad 13100, Pakistan.
  • Qadir KW; Renewable Energy Technology Department, Erbil Technology College, Erbil Polytechnic University, Erbil, Kurdistan 44001, Iraq.
  • Khan R; Computation Nanotechnology Research Lab (CNRL), Department of Physics, College of Education, Salahaddin University-Erbil, Erbil, Kurdistan 44002, Iraq.
  • Zafar Q; Department of Physics, University of Lakki Marwat, Lakki Marwat, Khyber Pakhtunkhwa 28440, Pakistan.
ACS Omega ; 9(1): 137-145, 2024 Jan 09.
Article en En | MEDLINE | ID: mdl-38239284
ABSTRACT
Pure and Ni-Fe-codoped Zn1 - 2xNixFexO (x = 0.01, 0.02, 0.03, and 0.04) nanoparticles were effectively synthesized using a sol-gel autocombustion procedure. The structural, optical, morphological, and magnetic properties were determined by using X-ray diffraction (XRD), ultraviolet-visible (UV-vis), scanning electron microscopy, and vibrating sample magnetometer techniques. The XRD confirmed the purity of the hexagonal wurtzite crystal structure. XRD analysis further indicated that Fe and Ni successfully substituted the lattice site of Zn and generated a single-phase Zn1-2xNixFexO magnetic oxide. In addition, a significant morphological change was observed with an increase in the dopant concentration by using high-resolution scanning electron microscopy. The UV-vis spectroscopy analysis indicated the redshift in the optical band gap with increasing dopant concentration signifying a progressive decrease in the optical band gap. The vibrating sample magnetometer analysis revealed that the doped samples exhibited ferromagnetic properties at room temperature with an increase in the dopant concentration. Dopant concentration was confirmed by using energy-dispersive X-ray spectroscopy. The current results provide a vital method to improve the magnetic properties of ZnO nanoparticles, which may get significant attention from researchers in the field of magnetic semiconductors.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Omega Año: 2024 Tipo del documento: Article País de afiliación: Pakistán Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Omega Año: 2024 Tipo del documento: Article País de afiliación: Pakistán Pais de publicación: Estados Unidos