Stable isotopes in the shell organic matrix for (paleo)environmental reconstructions.
Commun Chem
; 7(1): 16, 2024 Jan 18.
Article
en En
| MEDLINE
| ID: mdl-38238400
ABSTRACT
Stable isotope ratios of mollusc shell carbonates have long been used to reconstruct past environmental conditions. Although shells also contain organics, they are seldom used in (paleo)climatic studies. Here, we extract the acid-soluble and insoluble fractions of the organic matrix of modern Mytilus galloprovincialis shells from three sites along a coast-to-upper-estuary environmental gradient to measure their hydrogen (δ2H) and oxygen (δ18O) isotope compositions. Both organic fractions showed isotopic signatures significantly different from those of carbonate and water at each site, indicating the involvement of different fractionation mechanisms. The soluble fraction showed gradual differences in isotope values along the gradient, while the insoluble fraction showed δ2H-δ18O correlation regressions subparallel to the Global and Local Meteoric Water Lines. These results showed the great potential of the shell organic matrix stable isotopes as possible (paleo)environmental proxies, stimulating further research to better define the fractionation mechanisms involved.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Commun Chem
Año:
2024
Tipo del documento:
Article
País de afiliación:
Italia
Pais de publicación:
Reino Unido