Enantioselective synthesis of [1,1'-binaphthalene]-8,8'-diyl bis(diphenylphosphane) and its derivatives.

Tang, Yao; Yuan, Qingkai; Zhang, Sai; Wang, Jia-Yin; Surowiec, Kazimierz; Li, Guigen

Tang, Yao; Yuan, Qingkai; Zhang, Sai; Wang, Jia-Yin; Surowiec, Kazimierz; Li, Guigen.

Afiliación

Tang Y; Department of Chemistry and Biochemistry, Texas Tech University Lubbock Texas 79409-1061 USA guigen.li@ttu.edu.
Yuan Q; Department of Chemistry and Biochemistry, Texas Tech University Lubbock Texas 79409-1061 USA guigen.li@ttu.edu.
Zhang S; Department of Chemistry and Biochemistry, Texas Tech University Lubbock Texas 79409-1061 USA guigen.li@ttu.edu.
Wang JY; School of Pharmacy, Continuous Flow Engineering Laboratory of National Petroleum and Chemical Industry, Changzhou University Changzhou Jiangsu 213164 China.
Surowiec K; Department of Chemistry and Biochemistry, Texas Tech University Lubbock Texas 79409-1061 USA guigen.li@ttu.edu.
Li G; Department of Chemistry and Biochemistry, Texas Tech University Lubbock Texas 79409-1061 USA guigen.li@ttu.edu.

RSC Adv ; 14(4): 2792-2795, 2024 Jan 10.

Article en En | MEDLINE | ID: mdl-38234866

ABSTRACT

ABSTRACT

Two 8,8' disubstituted binaphthyl ligands have been designed and synthesized in 3.1% and 11.4% overall yield, respectively. X-ray structure analysis demonstrated that a unique chiral microenvironment was created. With the assistance of a new aggregation-induced polarization (AIP) technology, chiral aggregates were determined as the fraction of polar solvent increased in the nonpolar/polar solvent system, which indicated their potential in modern asymmetric synthesis and catalysis.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: RSC Adv Año: 2024 Tipo del documento: Article Pais de publicación: Reino Unido

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