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Product Peroxidation Inhibition in Methane Photooxidation into Methanol.
Cao, Yuehan; Huang, Zeai; Han, Chunqiu; Zhou, Ying.
Afiliación
  • Cao Y; National Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, 610500, China.
  • Huang Z; School of New Energy and Materials, Southwest Petroleum University, Chengdu, 610500, China.
  • Han C; School of New Energy and Materials, Southwest Petroleum University, Chengdu, 610500, China.
  • Zhou Y; School of New Energy and Materials, Southwest Petroleum University, Chengdu, 610500, China.
Adv Sci (Weinh) ; 11(12): e2306891, 2024 Mar.
Article en En | MEDLINE | ID: mdl-38234232
ABSTRACT
Methane photooxidation into methanol offers a practical approach for the generation of high-value chemicals and the efficient storage of solar energy. However, the propensity for C─H bonds in the desired products to cleave more easily than those in methane molecules results in a continuous dehydrogenation process, inevitably leading to methanol peroxidation. Consequently, inhibiting methanol peroxidation is perceived as one of the most formidable challenges in the field of direct conversion of methane to methanol. This review offers a thorough overview of the typical mechanisms involved radical mechanism and active site mechanism and the regulatory methods employed to inhibit product peroxidation in methane photooxidation. Additionally, several perspectives on the future research direction of this crucial field are proposed.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Adv Sci (Weinh) Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Alemania

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Adv Sci (Weinh) Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Alemania