Product Peroxidation Inhibition in Methane Photooxidation into Methanol.
Adv Sci (Weinh)
; 11(12): e2306891, 2024 Mar.
Article
en En
| MEDLINE
| ID: mdl-38234232
ABSTRACT
Methane photooxidation into methanol offers a practical approach for the generation of high-value chemicals and the efficient storage of solar energy. However, the propensity for CâH bonds in the desired products to cleave more easily than those in methane molecules results in a continuous dehydrogenation process, inevitably leading to methanol peroxidation. Consequently, inhibiting methanol peroxidation is perceived as one of the most formidable challenges in the field of direct conversion of methane to methanol. This review offers a thorough overview of the typical mechanisms involved radical mechanism and active site mechanism and the regulatory methods employed to inhibit product peroxidation in methane photooxidation. Additionally, several perspectives on the future research direction of this crucial field are proposed.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Adv Sci (Weinh)
Año:
2024
Tipo del documento:
Article
País de afiliación:
China
Pais de publicación:
Alemania