Tunable cyclic operation of dissipative molecular switches based on anion recognition.

Zhang, Xin; Mao, Lijun; He, Rongjing; Shi, Yanting; Li, Lingyi; Li, Shuo; Zhu, Chenghao; Zhang, Yanjing; Ma, Da

Zhang, Xin; Mao, Lijun; He, Rongjing; Shi, Yanting; Li, Lingyi; Li, Shuo; Zhu, Chenghao; Zhang, Yanjing; Ma, Da.

Afiliación

Zhang X; School of Pharmaceutical Engineering and Institute for Advanced Studies, Taizhou University, Taizhou 318000, China. dama@tzc.edu.cn.
Mao L; School of Pharmaceutical Engineering and Institute for Advanced Studies, Taizhou University, Taizhou 318000, China. dama@tzc.edu.cn.
He R; School of Pharmaceutical Engineering and Institute for Advanced Studies, Taizhou University, Taizhou 318000, China. dama@tzc.edu.cn.
Shi Y; School of Pharmaceutical Engineering and Institute for Advanced Studies, Taizhou University, Taizhou 318000, China. dama@tzc.edu.cn.
Li L; School of Pharmaceutical Engineering and Institute for Advanced Studies, Taizhou University, Taizhou 318000, China. dama@tzc.edu.cn.
Li S; School of Pharmaceutical Engineering and Institute for Advanced Studies, Taizhou University, Taizhou 318000, China. dama@tzc.edu.cn.
Zhu C; School of Pharmaceutical Engineering and Institute for Advanced Studies, Taizhou University, Taizhou 318000, China. dama@tzc.edu.cn.
Zhang Y; School of Pharmaceutical Engineering and Institute for Advanced Studies, Taizhou University, Taizhou 318000, China. dama@tzc.edu.cn.
Ma D; School of Pharmaceutical Engineering and Institute for Advanced Studies, Taizhou University, Taizhou 318000, China. dama@tzc.edu.cn.

Chem Commun (Camb) ; 60(9): 1180-1183, 2024 Jan 25.

Article en En | MEDLINE | ID: mdl-38193867

ABSTRACT

ABSTRACT

Artificial dissipative molecular switches based on anion recognition are of great importance to simulate biological functions and construct smart materials. Five activated carboxylic acids are used as chemical fuels for dissipative molecular switches, which consist of an imidazolium macrocyclic host and a carboxylate anionic guest. By choosing different types of chemical fuels and using varied fuel concentrations, the rates of cyclic operations are tunable. The operation is capable of undergoing at least three cycles.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido

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